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Efficient and color-stable solid-state white light-emitting electrochemical cells employing red color conversion layers

机译:使用红色转换层的高效且颜色稳定的固态白色发光电化学电池

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摘要

We report efficient and color-stable white light-emitting electrochemical cells (LECs) by combining single-layered blue-emitting LECs with red-emitting color conversion layers (CCLs) on the inverse side of the glass substrate. By judicious choosing of the red-emitting dye doped in CCLs, good spectral overlap between the absorption spectrum of the red-emitting dye and the emission spectrum of the blue-emitting emissive material results in efficient energy transfer and thus sufficient down-converted red emission at low doping concentrations of the red-emitting dye in the CCLs. Low doping concentration is beneficial in reducing self-quenching of the red-emitting dye, rendering efficient red emission. Electroluminescent (EL) measurements show that the peak external quantum efficiency and the peak power efficiency of the white LECs employing red CCLs reach 5.93% and 15.34 lm W~(-1), respectively, which are among the highest reported for white LECs. Furthermore, these devices exhibit bias-insensitive white EL spectra, which are required for practical applications, due to nondoped emissive layers. These results reveal that single-layered blue-emitting LECs combined with red-emitting CCLs are one of the potential candidates for efficient and color-stable white light-emitting devices.
机译:我们通过将单层发蓝光的LEC与玻璃基板反面上的发红光的颜色转换层(CCL)相结合,报告了高效且颜色稳定的发白光的电化学电池(LEC)。通过明智地选择掺入CCL中的红色发光染料,红色发光染料的吸收光谱与蓝色发光​​材料的发射光谱之间的良好光谱重叠可实现有效的能量转移,从而产生足够的下转换红色发射在CCL中掺杂低浓度的红色发光染料。低掺杂浓度有利于减少发红染料的自猝灭,从而有效地发出红光。电致发光(EL)测量表明,采用红色CCL的白色LEC的峰值外部量子效率和峰值功率效率分别达到5.93%和15.34 lm W〜(-1),是报道的白色LEC的最高值。此外,由于未掺杂发射层,这些器件还显示出偏置不敏感的白色EL光谱,这是实际应用所必需的。这些结果表明,与发红光的CCL结合使用的单层发蓝光的LEC是高效且颜色稳定的白光发射设备的潜在候选者之一。

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