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首页> 外文期刊>Organic Electronics >Electronic properties of transition metal phthalocyanines: The impact of the central metal atom (d~5-d~(10))
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Electronic properties of transition metal phthalocyanines: The impact of the central metal atom (d~5-d~(10))

机译:过渡金属酞菁的电子性质:中心金属原子的影响(d〜5-d〜(10))

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摘要

A combined spectroscopic investigation of transition metal phthalocyanines (TMPc's) has been carried out using electron energy-loss spectroscopy and photoemission spectroscopy. The results reveal an increasing impact of metal 3d states on the electronic properties of transition metal phthalocyanines on going from ZnPc to MnPc. In particular, the electronic states of FePc and MnPc close to the chemical potential are partly determined by a transition metal 3d state, which most likely has e_g symmetry.
机译:过渡金属酞菁(TMPc's)的组合光谱研究已使用电子能量损失光谱和光发射光谱进行。结果表明,从ZnPc到MnPc,金属3d态对过渡金属酞菁电子性能的影响越来越大。特别是,接近化学势的FePc和MnPc的电子状态部分由过渡金属3d状态决定,该状态最有可能具有e_g对称性。

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