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Interfacial electronic structures of WO_3-based intermediate connectors in tandem organic light-emitting diodes

机译:串联有机发光二极管中基于WO_3的中间连接器的界面电子结构

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摘要

Interfacial electronic structures of WO_3-based intermediate connectors used in tandem organic light-emitting diodes were studied with photoemission spectroscopy. Important factors controlling their functional effectiveness for charge carrier generation and injection were analyzed. By systematically characterizing the electronic properties and chemical structures for various intermediate connectors, it is identified that the WO_3 interlayer is capable of pronouncedly modifying the energy level alignment of the intermediate connectors and thereby the adjacent emission units. Substantial interface dipole and energy level bending caused by the oxide connector are shown to be beneficial to carrier injection into the suitable molecular energy levels of adjoining emission units.
机译:通过光发射光谱研究了串联有机发光二极管中基于WO_3的中间连接器的界面电子结构。分析了控制它们对电荷载流子产生和注入的功能有效性的重要因素。通过系统地表征各种中间连接器的电子性质和化学结构,可以确定WO_3中间层能够显着改变中间连接器的能级排列,从而改变相邻的发射单元。氧化物连接器引起的大量界面偶极子和能级弯曲被证明有利于将载流子注入相邻发射单元的合适分子能级中。

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  • 来源
    《Organic Electronics》 |2010年第9期|P.1578-1583|共6页
  • 作者单位

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 2/5123, PR China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 2/5123, PR China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 2/5123, PR China;

    Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 2/5123, PR China;

    Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR, PR China;

    Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR, PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    WO_3; intermediate connector; tandem OLED; energy level alignment;

    机译:WO_3;中间连接器;串联OLED;能级对准;

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