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Development of new active nanocomposite packaging films containing polyhedral oligomeric silsesquioxane for walnut (Juglans regia L.) kernel packaging

机译:含有多面体低聚硅氧烷的新型活性纳米复合材料包装薄膜核桃(Juglans Regia L.)内核包装

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Active nanocomposite films made from low-density polyethylene (LDPE) and polyhedral oligomeric silsesquioxane (POSS) were prepared as of food packaging material for walnut kernels (Juglans regia L.) oil protection against lipid oxidation. N-Phenylaminopropyl-POSS (NP-POSS), octaammonium-POSS (QA-POSS) and methacryl-POSS (M-POSS) were utilized as convenient additives. Intact and crushed walnut kernels were stored in conditions set to accelerate oxidation (24 h of light, 38 degrees C, and 33% RH). On the 14th day, peroxide value (PV) was determined as 14.13 meq O-2/kg in intact walnut kernel oil (WKO), whereas the PV of walnuts was measured as 5.94 meq O-2/kg and 7.95 meq O-2/kg wrapped with 5 wt% NP-POSS and 3 wt% QA-POSS containing the film, respectively. At the end of the storage, K-232 values were measured as 4.42 and 6.12 packaged with control films, whereas K-232 values ranged 2.72 and 3.14 in samples packaged with 5 wt% NP-POSS. Similarly, K-232 value of WKO wrapped with QA-POSS containing films was detected as 2.89 and 3.20 in intact and crushed walnut samples, respectively. The p-anisidine value of WKO wrapped with pure LDPE reached 4.86 and 7.33 for WKO obtained from the intact and crushed walnut kernel, and the lowest p-anisidine values observed intact (2.07) and crushed (3.84) samples of packaged with 5 wt% NP-POSS, respectively. The results have shown that novel nanocomposite food packaging films, including NP-POSS and QA-POSS, for vacuum-packed walnut kernels are sufficient to protect against oxidation.
机译:由低密度聚乙烯(LDPE)和多面体低聚倍半硅氧烷(POSS)制成的活性纳米复合膜被制备为核桃仁(Juglans Regia L)的食品包装材料(Juglans Regia L.)油保护免受脂质氧化。 N-苯基氨基丙基 - POSS(NP-POSS),octaMMONIUM-POSS(QA-POSS)和Methacryl-POSS(M-POSS)作为方便的添加剂。完整和粉碎的核桃核在设定的条件下储存以加速氧化(24小时,38℃和33%RH)。在第14天,在完整的核桃仁油(WKO)中,将过氧化物值(PV)确定为14.13meq O-2 / kg,而核桃的PV被测量为5.94meq O-2 / kg和7.95 meq O-2 / kg分别用5wt%的NP-pOLD和3wt%qa-poss缠绕,含有薄膜。在储存的末端,k-232值被测量为4.42和6.12,其包装在用对照膜,而K-232值范围为2.72和3.14,样品中包装的5wt%np-poss。类似地,用QA-POSS薄膜包裹的WKO的K-232值分别在完整和碎核桃样品中检测为2.89和3.20。用纯LDPE包裹的WKO的p-茴香氨酸值达到4.86和7.33,用于从完整和碎核桃核中获得的WKO,并且观察到完整(2.07)和粉碎(3.84)包装的粉碎(3.84)的最低p-茴香氨酸值分别为np-poss。结果表明,用于真空包装的核桃核的新型纳米复合食品包装薄膜,包括NP-POSS和QA-POSS,足以防止氧化。

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