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Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate

机译:六价胍盐硫酸钒钒中V 3 + 离子的拉曼光谱和ESR光谱的理论解释

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The Raman spectra and electronic spin resonance (ESR) parameters (spin-Hamiltonian parameter g factors, zero-field splitting parameter D, and hyperfine structure constant A) for the trigonal V3+ centers in salt guanidinium vanadium sulfate hexahydrate (GVSH) are calculated from the complete diagonalization (of energy matrix) method. The theoretical results are in agreement with the experimental findings and the trigonal crystal-field parameters are determined. The difficulty in explaining ESR parameters of V3+ in GVSH is removed.View full textDownload full textKeywordscrystal-field theory, Raman spectra, ESR, (C(NH2)3V(SO4)2 ·6H2O, V3+ Related var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/09500839.2012.681709
机译:盐胍钒钒中三角V 3 + 中心的拉曼光谱和电子自旋共振(ESR)参数(自旋哈密顿参数g因子,零场分裂参数D和超精细结构常数A)六水合硫酸盐(GVSH)由完全对角化(能量矩阵)方法计算得出。理论结果与实验结果吻合,确定了三角晶场参数。消除了解释GVSH中V 3 + 的ESR参数的困难。查看全文下载全文关键字晶体场理论,拉曼光谱,ESR,(C(NH2)3V(SO4)2· 6H2O,V3 +相关变量addthis_config = {ui_cobrand:“泰勒和弗朗西斯在线”,servicescompact:“ citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,更多”,发布ID:“ ra-4dff56cd6bb1830b” };添加到候选列表链接永久链接http://dx.doi.org/10.1080/09500839.2012.681709

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