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首页> 外文期刊>Physica status solidi >Mid-infrared emission from Er~(3+) and energy transfer in Er~(3+)-Yb~(3+) and Er~(3+)-Nd~(3+) co-doped Ga_2S_3-GeS_2-Sb_2S_3 glasses
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Mid-infrared emission from Er~(3+) and energy transfer in Er~(3+)-Yb~(3+) and Er~(3+)-Nd~(3+) co-doped Ga_2S_3-GeS_2-Sb_2S_3 glasses

机译:Er〜(3+)的中红外发射和Er〜(3 +)-Yb〜(3+)和Er〜(3 +)-Nd〜(3+)的能量掺杂共掺杂Ga_2S_3-GeS_2-Sb_2S_3眼镜

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摘要

The radiative and nonradiative transitions of the first three excited levels of Er~(3+) doped in Ga_2S_3-GeS_2-Sb_2S_3 glass were investigated. Particularly, we focused on the ~4I_(9/2) and ~4I_(11/2) which are the initial and final levels of mid-infrared emission around 4 μm. The effects of energy transfer from these levels to co-doped rare-earth ions, Yb~(3+) and Nd~(3+), were estimated. The population of the final level, ~4I_(11/2), was efficiently quenched by the energy transfer to the Yb~(3+), ~2F_(5/2) level. This leads to the population inversion between the initial and final levels. In the Nd~(3+)-co-doped glass, on the contrary, the initial level, ~4I_(9/2), was more rapidly quenched than the final level, ~4I_(11/2), through the energy transfer to Nd~(3+), ~4F_(5/2) + ~2H_(9/2).
机译:研究了Ga_2S_3-GeS_2-Sb_2S_3玻璃中掺杂的Er〜(3+)的前三个激发能级的辐射跃迁和非辐射跃迁。尤其是,我们专注于〜4I_(9/2)和〜4I_(11/2),它们是4μm左右的中红外发射的初始和最终水平。估计了从这些能级到共掺杂稀土离子Yb〜(3+)和Nd〜(3+)的能量转移效应。通过能量转移到Yb〜(3+)~~ 2F_(5/2)能级有效地淬灭了最终能级〜4I_(11/2)的种群。这导致人口数量在初始水平和最终水平之间倒置。相反,在掺Nd〜(3+)的玻璃中,初始能级〜4I_(9/2)通过能量比最终能级〜4I_(11/2)更快地淬灭。转移到Nd〜(3+),〜4F_(5/2)+〜2H_(9/2)。

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  • 来源
    《Physica status solidi》 |2011年第12期|p.2809-2813|共5页
  • 作者单位

    Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan;

    Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan;

    Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan;

    Division of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    energy transfer; infrared emission; rare-earth elements; sulfide glasses;

    机译:能量转移;红外发射;稀土元素;硫化玻璃;

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