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Colloidal Gels Assembled via a Temporary Interfacial Scaffold

机译:通过临时界面支架组装的胶体凝胶

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摘要

The liquid-liquid phase separation of a binary solvent can be arrested by colloidal particles trapped at the interface [K. Stratford et al., Science 309, 2198 (2005)]. We show experimentally that the colloidal network so formed can remain stable after fully remixing the liquids, creating a new type of gel in which colloids in a single-phase solvent have locally planar coordination. We argue that this structure is likely maintained by primary-minimum Derjaguin-Landau-Verweg-Overbeek bonding of our charged colloids, created under strong compression by capillary forces. We present simulation evidence that the combination of a short-ranged attraction with a repulsive barrier can strongly stabilize such locally planar gels.
机译:二元溶剂的液-液相分离可以通过界面处捕获的胶体颗粒来阻止。 Stratford等,Science 309,2198(2005)]。我们实验表明,这样形成的胶体网络在完全混合液体后可以保持稳定,从而形成一种新型的凝胶,其中单相溶剂中的胶体具有局部平面配位。我们认为,这种结构很可能是由毛细作用力在强烈压缩下产生的带电胶体的最小-最小Derjaguin-Landau-Verweg-Overbeek键保持的。我们目前的模拟证据表明,短程吸引力与排斥屏障的结合可以强烈稳定这种局部平面的凝胶。

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  • 来源
    《Physical review letters》 |2009年第25期|255502.1-255502.4|共4页
  • 作者单位

    SUPA, School of Physics and Astronomy, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom;

    SUPA, School of Physics and Astronomy, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom;

    SUPA, School of Physics and Astronomy, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom;

    SUPA, School of Physics and Astronomy, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    self-assembly; powders, porous materials; colloids;

    机译:自组装;粉末;多孔材料;胶体;

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