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Electronic conductivity in Berlin green and Prussian blue

机译:柏林绿和普鲁士蓝的电子电导率

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摘要

We report the temperature dependent (100-300 K) conductivity of Berlin green and Prussian blue powders. The method of electronic conduction in vacuum dried Berlin green is identified as hopping of localized electrons and vacuum dried Prussian blue is reaffirmed as an insulator. The assignment of the conduction mechanism is based upon fits to the experimental data, and the different conductivities of the two samples can be understood in terms of both molecular and simple crystalline energy levels of the solids.
机译:我们报告了柏林绿和普鲁士蓝粉末的温度依赖性(100-300 K)电导率。真空干燥的柏林绿中的电子传导方法被确定为局域电子的跳跃,真空干燥的普鲁士蓝被确认为绝缘体。传导机制的分配基于对实验数据的拟合,并且可以根据固体的分子能级和简单结晶能级来理解两个样品的不同电导率。

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