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Violation of Hund's third rule in structurally disordered ferromagnets

机译:在结构无序的铁磁体中违反了洪德第三规则

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摘要

Violation of Hund's third rule caused by structural disorder is observed for the induced magnetic moment of Zr, using x-ray magnetic circular dichroism. The induced spin and orbital magnetic moments are antiparallel in the crystalline state, but parallel in an amorphous state of the investigated Co- and Fe-based materials. First-principles calculations are used to provide physical insight into the dependency of the spin-orbit coupling on the interatomic distance and coordination number.
机译:使用X射线磁性圆二色性观察到Zr的感应磁矩违反了由结构紊乱引起的Hund第三规则。在研究的钴基和铁基材料中,感应的自旋和轨道磁矩在晶体状态下反平行,但在非晶态下平行。第一性原理计算用于提供对自旋轨道耦合对原子间距离和配位数的依赖性的物理了解。

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