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首页> 外文期刊>Physical review. B, Condensed Matter And Materials Physics >Role of hydrogen bonds in the supercooled dynamics of glass-forming liquids at high pressures
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Role of hydrogen bonds in the supercooled dynamics of glass-forming liquids at high pressures

机译:氢键在高压下玻璃形成液体的过冷动力学中的作用

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摘要

The effect of pressure on the dynamics of supercooled liquids shows a variety of remarkable similarities for different glass-forming systems. However, an important group of liquids, characterized by hydrogen-bond interactions, show some deviations from these general behaviors. To investigate this, we use broadband dielectric spectroscopy to study the temperature dependent dynamics of a supercooled hydrogen bonded oligomeric glycol and its non-hydrogen-bonded analog over a wide range of pressures. With the chosen model system, we are able to directly link the presence of hydrogen bonding to deviations from the general pattern of the pressure response of supercooled dynamics.
机译:压力对过冷液体动力学的影响对于不同的玻璃成型系统显示出各种显着的相似性。但是,以氢键相互作用为特征的一组重要液体显示出与这些一般行为有所偏离。为了对此进行研究,我们使用宽带介电谱研究了在很宽的压力范围内过冷氢键低聚乙二醇及其非氢键类似物的温度依赖性动力学。通过选择的模型系统,我们能够将氢键的存在与过冷动力学压力响应一般模式的偏差直接联系起来。

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