Electron Paramagnetic Resonance Of Sulfur At A Split-vacancy Site In Diamond

J. M. Baker; J. A. van Wyk; J. P. Goss; P. R. Briddon

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Electron Paramagnetic Resonance Of Sulfur At A Split-vacancy Site In Diamond

机译：金刚石分裂空位处硫的电子顺磁共振

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In natural diamonds a sulfur-related paramagnetic center labeled W31 has been previously tentatively assigned to an interstitial sulfur species in a positive charge state. However, we show by combining an assessment of available experimental data and density-functional simulations that the hyperfine tensors can be attributed to a defect made up from sulfur at the center of a divacancy, the so-called split vacancy, in the negative charge state. These acceptors are highly likely to be formed in S-implanted material and are a likely cause for high resistivity in material implanted with sulfur in the attempt to produce n-type conduction.

机译：在天然钻石中，预先将标记为W31的与硫有关的顺磁中心暂时分配给处于正电荷状态的填隙硫。但是，我们通过结合可用实验数据的评估和密度泛函模拟表明，超细张量可归因于由处于负电荷状态的空位中心处的硫（所谓的分裂空位）引起的缺陷。。这些受体很可能在注入S的材料中形成，并且可能是在注入硫的材料中试图产生n型导电的材料中高电阻率的原因。

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《Physical review》 |2008年第23期|381-389|共9页
作者
J. M. Baker; J. A. van Wyk; J. P. Goss; P. R. Briddon;
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theories and models of crystal defects; elemental semiconductors;

机译：晶体缺陷的理论和模型;元素半导体;

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4. We have investigated the interface and oxide defects in SiC/SiO_2 by electron paramagnetic resonance spectroscopy (EPR) using oxidised porous SiC of 4H and 6H polytypes. Two paramagnetic defects generated by 1000 deg C furnace oxidation in dry oxygen [C] . Krishna C. Saraswat, Chi On Chui, Paul C. Mclntyre, the International Symposium of Electrochemical Society . 2003

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5. Development of an electron paramagnetic resonance system for a single nitrogen-vacancy center in diamond [D] . Stepanov, Viktor 2014

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6. Advanced Paramagnetic Resonance Spectroscopies of Iron-Sulfur Proteins: Electron Nuclear Double Resonance (ENDOR) and Electron Spin Echo Envelope Modulation (ESEEM) [O] . George E. Cutsail III, Joshua Telser, Brian M. Hoffman -1

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7. Advanced paramagnetic resonance spectroscopies of iron–sulfur proteins: Electron nuclear double resonance (ENDOR) and electron spin echo envelope modulation (ESEEM) [O] . Cutsail George E., Telser Joshua, Hoffman Brian M. 2015

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8. Electron Paramagnetic Resonance in Low-Temperature Electron-Irradiated Diamond. [R] . Brosious, P. R., Corbett, J. W., Bourgoin, J. C. 1976

机译：低温电子辐照金刚石中的电子顺磁共振。

Electron Paramagnetic Resonance Of Sulfur At A Split-vacancy Site In Diamond

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