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Thermoelectric transport properties of borophane

机译:硼烷的热电输运性质

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摘要

I theoretically study the influence of impurity scattering on the electrical and thermal transport of borophane layer, a two-dimensional anisotropic Dirac semimetal with two tilted and anisotropic Dirac cones. In a systematic framework, I have calculated the electrical conductivity and thermoelectric coefficients of borophane in the presence of the short-range, long-range charged impurity and the short-range electromagnetic (SREM) scatterers, by using the exact solution of the Boltzmann transport equation within the linear-response theory. Contrary to the large electron-hole asymmetry in borophane, its electron-hole conductivity is nearly symmetric. Interestingly, in the case of short-range scattering, just like graphene, the conductivities of borophane were found to have constant values, independent of the chemical potential, while the conductivities of the SREM scatterers are linearly dependent on the chemical potential. Regardless of the impurity type, the electrical conductivity of borophane is highly anisotropic, while the Seebeck coefficient and figure of merit (ZT) are isotropic. Along with the ambipolar nature of the borophane thermopower, a very high value of ZT around unity is obtained at room temperature, due to the large asymmetry between electrons and holes in borophane. More importantly, borophane attains its maximum value of ZT at very low chemical potentials, in the vicinity of the charge neutrality point. In comparison to phosphorene, a highly unique anisotropic 2D material, borophane with a higher anisotropy ratio (sigma(xx)/sigma(yy) similar to 10) is an unprecedented anisotropic material. This high anisotropy ratio together with the large figure of merit suggest that borophane is promising for the thermoelectric applications and transport switching in the Dirac transport channels.
机译:我从理论上研究了杂质散射对具有两个倾斜且各向异性的狄拉克锥的二维各向异性狄拉克半金属硼烷层的电和热输运的影响。在一个系统的框架中,通过使用玻尔兹曼输运的精确解,我计算了在存在短程,长程带电杂质和短程电磁(SREM)散射体的情况下硼烷的电导率和热电系数线性响应理论中的方程。与硼烷中大的电子-空穴不对称性相反,它的电子-空穴传导率几乎是对称的。有趣的是,在短程散射的情况下,就像石墨烯一样,发现硼烷的电导率具有恒定值,而与化学势无关,而SREM散射体的电导率则线性地取决于化学势。不管杂质类型如何,硼烷的电导率都是高度各向异性的,而塞贝克系数和品质因数(ZT)是各向同性的。连同硼烷热电势的双极性性质,由于硼烷中电子与空穴之间的不对称性很大,因此在室温下可获得很高的ZT值。更重要的是,硼烷在非常低的化学势上在电荷中和点附近达到ZT的最大值。与磷烯相比,高度独特的各向异性2D材料,具有更高各向异性比(σ(xx)/ sigma(yy)类似于10)的硼烷是一种前所未有的各向异性材料。这种高的各向异性比率以及较高的品质因数表明,硼烷有望在Dirac传输通道中用于热电应用和传输转换。

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  • 来源
    《Physical review》 |2019年第23期|235413.1-235413.11|共11页
  • 作者

    Zare Moslem;

  • 作者单位

    Univ Yasuj, Dept Phys, Yasuj 75914353, Iran;

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  • 正文语种 eng
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