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首页> 外文期刊>Polymer Degradation and Stability >Dependence of yields of thermal degradation products of poly(methyl methacrylate-co- methacrylic salts of alkaline metals) on dyad, triad and tetrad composition of macromolecules
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Dependence of yields of thermal degradation products of poly(methyl methacrylate-co- methacrylic salts of alkaline metals) on dyad, triad and tetrad composition of macromolecules

机译:聚(甲基丙烯酸甲酯-碱金属共丙烯酸甲基丙烯酸盐)的热降解产物的产率与大分子的二元组,三元组和四元组组成的关系

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摘要

A quantitative relationship has been established between yields of thermal degradation products (methyl alcohol and methyl methacrylate) of methacry- late copolymers with lithium, sodium and potassium salts of methacrylic acid and component structure of copolymer macromolecules. The differences between experimental and estimated values of ethyl alcohol yields were substantilally reduced by changing from estimation methods based on the dyad copolymer composition to methods based on the triad and tetrad copolymer composition.
机译:在甲基丙烯酸共聚物与甲基丙烯酸的锂盐,钠盐和钾盐的热降解产物(甲醇和甲基丙烯酸甲酯)的产率与共聚物大分子的组分结构之间建立了定量关系。通过将基于二元共聚物组成的估算方法改为基于三元共聚物和四元共聚物组成的方法,可以大幅减少乙醇收率的实验值与估算值之间的差异。

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