Network characteristics of hydrogenated nitrile butadiene rubber networks obtained by radiation crosslinking by electron beam

Sophie Perraud; rnMarie-France Vallat; rnMarie-Odile David; rnJerzy Kuczynski

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Network characteristics of hydrogenated nitrile butadiene rubber networks obtained by radiation crosslinking by electron beam

机译：电子束辐射交联获得的氢化丁腈橡胶网的网络特性

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The effects of high-energy radiation on hydrogenated nitrile butadiene rubber (HNBR) copolymer structure and properties were studied. Characterization by FTIR spectroscopy, swelling and mechanical measurements of irradiated and un-irradiated sample permit us to correlate the change in structure with properties. The modifications obtained are dependent on the radiation dose of the incident electron beam. FTIR spectroscopy in absorption mode shows that irradiation of HNBR first induces trans-vinylene bond formation and secondly small amounts of carbonyl (C=O) groups. Moreover, more significant changes were observed with swelling method and mechanical behaviour showing the effect of cross-linking on the elastomer.

机译：研究了高能辐射对氢化丁腈橡胶（HNBR）共聚物结构和性能的影响。通过FTIR光谱表征，辐照和未辐照样品的溶胀和机械测量，可以使我们将结构变化与特性相关联。所获得的修改取决于入射电子束的辐射剂量。吸收模式的FTIR光谱表明，HNBR的辐射首先引起反式亚乙烯基键的形成，其次引起少量的羰基（C = O）。此外，在溶胀方法和机械性能方面观察到了更显着的变化，表明了交联对弹性体的影响。

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《Polymer Degradation and Stability》 |2010年第9期|p.1495-1501|共7页
作者
Sophie Perraud; rnMarie-France Vallat; rnMarie-Odile David; rnJerzy Kuczynski;
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作者单位

Institut de Science des Materiaux de Mulhouse (LRC 7228 CNRS - Universite de Haute-Alsace), 15, rue Jean Starcky, BP 2488 -68057 Mulhouse, Cedex, France;

rnInstitut de Science des Materiaux de Mulhouse (LRC 7228 CNRS - Universite de Haute-Alsace), 15, rue Jean Starcky, BP 2488 -68057 Mulhouse, Cedex, France;

rnIUT Evry Val d'Essonne Departement Sciences et Genie de Materiaux (SGM), Batiment des Sciences, Rue du Pere Jarlan, 91025 EVRY, Cedex,, France Mac Dermid GraphicArts, Rue de l'Industrie BP 70 - 68702 Cernay, Cedex, France;

rnMac Dermid GraphicArts, Rue de l'Industrie BP 70 - 68702 Cernay, Cedex, France;

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正文语种 eng
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关键词
hydrogenated nitrile butadiene rubber (HNBR); crosslinking; electron beam; radiation; mechanical properties; network;

机译：氢化丁腈橡胶（HNBR）;交联电子束;辐射;机械性能网络;

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专利

1. Electron beam and gamma radiation crosslinking of Hydrogenated acrylonitrile-butadiene rubber [J] . J.M.Bik, W.M.Rzymski Gummi, Fasern, Kunststoffe . 2006,第8期

机译：氢化丙烯腈-丁二烯橡胶的电子束和γ射线交联
2. Characterization of Organoclay-Networks Modified Low-Temperature Hydrogenated Nitrile Butadiene Rubber Composites [J] . Jihua Zhang, Weitao Zao, Lifeng Wang Polymer Composites . 2014,第7期

机译：有机粘土网络改性的低温氢化丁腈橡胶复合材料的表征
3. Thermal-oxidative aging behaviors of shape memory nitrile butadiene rubber composite with dual crosslinking networks [J] . Jihua Zhang, Chao Wang, Fengbo Chen, Polymer Degradation and Stability . 2020,第Sepa期

机译：双交联网络的形状记忆丁二烯橡胶复合材料热氧化老化行为
4. Electron Beam Modification and Crosslinking: Influence of Nitrile and Carboxyl Contents and Level of Unsaturation on Structure and Properties of Nitrile Rubber (Paper No. 69) [C] . V. Vijayabaskar, S. Bhattacharya, V. K. Tikku, American Chemical Society Rubber Division Meeting . 2004

机译：电子束改性和交联：腈和羧基含量及不饱和度对丁腈橡胶结构和性能的影响（69号论文）
5. Effect of zinc oxide particle size on the mechanical properties of carboxylated nitrile and carboxylated styrene-butadiene rubbers. [D] . Hua, Kuo-Chih. 2003

机译：氧化锌粒度对羧化丁腈橡胶和羧化丁苯橡胶力学性能的影响。
6. Actuator Performance of a Hydrogenated CarboxylatedAcrylonitrile–Butadiene Rubber/Silica-Coated BaTiO [O] . Ryosuke Matsuno, Takamasa Ito, Shigeaki Takamatsu, 2021

机译：氢化羧化的致动器性能丙烯腈 - 丁二烯橡胶/二氧化硅涂层BATIO
7. The effect of hydrocarbon ageing on the mechanical properties, apparent crosslink density and CO2 diffusion of a hydrogenated nitrile butadiene rubber (HNBR) [O] . Ben Alcock, Thijs A. Peters, Rune H. Gaarder, 2015

机译：烃老化对氢化丁腈橡胶（HNBR）的机械性能，表观交联密度和CO2扩散的影响
8. Composite Rubber Networks. Part I. Vulcanisates Based on Nitrile and Silicone Rubbers [R] . Thomas, D. K., Day, J. 1972

机译：复合橡胶网络。第一部分基于腈和硅橡胶的硫化橡胶

Network characteristics of hydrogenated nitrile butadiene rubber networks obtained by radiation crosslinking by electron beam

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