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首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America >Oxidation states of the manganese cluster during the flash-induced S-state cycle of the photosynthetic oxygen-evolving complex
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Oxidation states of the manganese cluster during the flash-induced S-state cycle of the photosynthetic oxygen-evolving complex

机译:光合作用的放氧复合物在闪光诱导的S-态循环中锰簇的氧化态

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摘要

The Mn K-edge x-ray absorption spectra for the pure S states of the tetranuclear Mn cluster of the oxygen-evolving complex of photosystem II during flash- induced S-state cycling have been determined. The relative S-state populations in samples given 0, 1, 2, 3, 4, or 5 flashes were determined from fitting the flash-induced electron para- magnetic resonance (EPR) multiline signal oscillation pattern to the Kok model. The edge spectra of samples given 0, 1, 2, or 3 flashes were combined with EPR information to calculate the pure S-state edge spectra.
机译:已确定了在闪光诱导的S状态循环过程中,光系统II的释氧复合物的四核Mn簇的纯S状态的Mn K边缘x射线吸收光谱。通过将闪光感应电子顺磁共振(EPR)多线信号振荡模式拟合到Kok模型,可以确定给出了0、1、2、3、4或5次闪光的样品中的相对S状态种群。将给出0、1、2或3次闪光的样品的边缘光谱与EPR信息结合起来,以计算纯S态边缘光谱。

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