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首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America >Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation
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Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation

机译:一维晶格气体和Brunauer-Emmett-Teller方程的吸附

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摘要

An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation - namely, Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point. However, neither model should be considered realistic for experimental adsorption systems.
机译:一维晶格气体的吸附的精确处理用于消除和纠正Brunauer-Emmett-Teller(BET)方程中众所周知的不一致问题-即,不考虑Gibbs过量吸附并且Gibbs积分发散在过渡点。但是,对于实验性吸附系统,这两个模型都不应被认为是现实的。

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