Octahydriodo diborane (B_2H_8) and its protonated cations containing five-, six-,and seven-coordinate boron atoms

George A. Olah; G. K. Surya Prakash; Golam Rasul

首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America >Octahydriodo diborane (B_2H_8) and its protonated cations containing five-, six-,and seven-coordinate boron atoms

【24h】

Octahydriodo diborane (B_2H_8) and its protonated cations containing five-, six-,and seven-coordinate boron atoms

机译：八氢乙硼烷（B_2H_8）及其质子化阳离子，含五，六和七配位硼原子

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Structures of octahydriodo diborane (B_2H_8) 1 and its protonated 3, diprotonated 5, triprotonated 6, and tetraprotonated 7 ions were found to be calculationally viable minima at the MP2/cc-pVTZ level of theory. Each structure contains two-electron three-center (2e-3c) bonds. The protonation of 1 to form 3 was found to be strongly exothermic by 176.0 kcal/mol. Subsequent protonation of 3 to form 5 was also found to be exothermic by 28.4 kcal/mol. Further protonation of 5 to form 6 was, however, computed to be en-dothermic by 122.0 kcal/mol whereas protonation of 6 to form 7 was again highly endothermic by 238.8 kcal/moL Deprotonation barriers of the ions were also computed.

机译：在理论上MP2 / cc-pVTZ水平上，发现八氢乙硼烷（B_2H_8）1及其质子化3，二质子化5，三重质子化6和四质子化7离子的结构在计算上是可行的最小值。每个结构都包含两个电子的三中心键（2e-3c）。发现1到3的质子化以176.0kcal / mol强烈放热。还发现随后的3质子化为5的质子以28.4 kcal / mol放热。然而，进一步计算出5形成6的质子为122.0 kcal / mol的吸热峰，而6形成7的质子又通过238.8 kcal / moL的高吸热峰也被计算出来。

著录项

来源
《Proceedings of the National Academy of Sciences of the United States of America》 |2012年第18期|p.6825-6828|共4页
作者
George A. Olah; G. K. Surya Prakash; Golam Rasul;
展开▼
作者单位

Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661;

Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661;

Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661;

展开▼
收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类
关键词
ab initio; boronium; hypercoordinate; cations; polycations;

机译：从头开始硼超坐标阳离子;聚阳离子;

相似文献

外文文献
中文文献
专利

1. ~(29)Si NMR Spectroscopic Study of a Series of Five-,Six-,and Seven-Coordinate Silicon Compounds [J] . N.P.Erchak, K.Pypowski, E.Liepins Russian Journal of General Chemistry . 2007,第12期

机译：一系列五，六，七配位硅化合物的〜（29）Si NMR光谱研究
2. Synthesis and structural characterization of five-, six-, and seven-coordinate mononuclear manganese(II) complexes with N-tridentate ligands [J] . Baffert C, Romero I, Pecaut J, Inorganica Chimica Acta . 2004,第12期

机译：具有三三齿配体的五，六和七配位单核锰（II）配合物的合成和结构表征
3. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF FIVE-, SIX-, AND SEVEN-COORDINATE MANGANESE(II) COMPLEXES OF THE TRIPODAL LIGAND TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE [J] . Lah MS., Chun H. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第9期

机译：三联配体三（2-苯并咪唑基甲基）胺的五，六和七配位锰（II）配合物的合成和结构表征
4. Cp~*Rh Complex-Catalyzed Synthesis of Five-,Six-,and Seven-Membered Ring Lactams from Amino Alcohols [C] . Ken-ichi Fuiila, Yoshinori Takahashi, Maki Owaki, Symposium on Organometallic Chemistry . 2004

机译：CP〜* rh复合催化合成氨基醇的五，六个和七元环内酰胺的合成
5. Octahydriodo diborane (B2H8) and its protonated cations containing five- six- and seven-coordinate boron atoms [O] . George A. Olah, G. K. Surya Prakash, Golam Rasul 2012

机译：八氢乙硼烷（B2H8）及其质子化阳离子含五六和七配位的硼原子
6. Octahydriodo diborane (B2H8) and its protonated cations containing five-, six-, and seven-coordinate boron atoms [O] . G. A. Olah, G. K. Surya Prakash, G. Rasul 2012

机译：OctaHydriodo二硼烷（B2H8）及其含有五个，六个和七坐标硼原子的质子化阳离子
7. Transition-Metal-Promoted Reactions of Boron Hydrides. 7. Platinum(II) Bromide Catalyzed Cage Growth and Dehydrocoupling Reactions of Diborane with Small Polyhedral Carboranes and Boranes: Synthesis of a New Arachno Carborane, 5,6-C2B6H12, and the Diborane-Coupled Compounds 2:1', 2'-(1,6-C2B4H5)(B2H5) and 2:1',2'-(B5H8)(B2H5). [R] . Corcoran, E. W., Sneddon, L. G. 1985

机译：过渡金属促进的氢化硼反应。 7.铂（II）溴化物催化的笼型生长和乙硼烷与小多面体碳硼烷和硼烷的脱氢偶联反应：合成新的arachno Carborane，5,6-C2B6H12和乙硼烷偶联化合物2：1'，2' - （ 1,6-C2B4H5）（B2H5）和2：1'，2' - （B5H8）（B2H5）。

Octahydriodo diborane (B_2H_8) and its protonated cations containing five-, six-,and seven-coordinate boron atoms

摘要

著录项

相似文献

相关主题

期刊订阅