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首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America >Archimedean solids: Transition metal mediated rational self -assembly of supramolecular- truncated tetrahedra
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Archimedean solids: Transition metal mediated rational self -assembly of supramolecular- truncated tetrahedra

机译:阿基米德固体:过渡金属介导的超分子截短的四面体的合理自组装

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摘要

A family of nanoscale-sized supramolecular cage compounds with a polyhedral framework is prepared by self-assembly from tritopic building blocks and rectangular corner units via noncovalent co- ordination interactions. These highly symmetrical cage compounds are described as face-directed, self-assembled truncated tetrahe- dra with Td symmetry.
机译:具有三面体骨架的纳米级超分子笼状化合物家族是通过三价结构单元和矩形角单元通过非共价配位相互作用自组装制备的。这些高度对称的笼状化合物被描述为具有Td对称性的面定向自组装截短的四面体。

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