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Effects of CO

机译:一氧化碳的影响

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摘要

To reveal the effects of CO2 and CO on the reduction of NO in oxy-fuel fluidised bed combustion, NO-CO reduction catalysed by calcined limestone and NO-char reduction were studied in a suspension-bed reactor under CO2 or N-2 atmosphere with the CO concentration varied from 0.28 to 1.88%. Results showed that the calcined limestone is an effective catalyst for NO-CO reduction. The activation energy of NO-CO reduction over calcined limestone was 157-164 kJ/mol at low temperature (600-800 degrees C) and decreased to 58.7-102.1 kJ/mol at high temperature (800-100 degrees C). In CO2 atmosphere, the NO conversion ratio was nearly zero during the NO-CO reduction process, and for NO-char reduction, the NO conversion ratio in CO2 was lower than that in N-2. However, CO showed promotion effect on NO reduction. In NO-CO reduction process, as the CO concentration increased from 0.28% to 1.88%, the NO reduction ratio increased from 0.40 to 0.75. For NO-char reduction in N-2, the NO conversion ratio was obviously higher when 1% CO was introduced, and the promotion effect of CO became weaker as the temperature increased. Moreover, the promoting effect of CO was inhibited in CO2 atmosphere.
机译:为了揭示CO2和CO对氧燃料流化床燃烧中NO还原的影响,在CO2或N-2气氛下,在悬浮床反应器中研究了煅烧石灰石催化的NO-CO还原和NO炭还原。 CO浓度从0.28到1.88%不等。结果表明,煅烧石灰石是一种有效的还原NO-CO的催化剂。煅烧石灰石上的NO-CO还原的活化能在低温(600-800摄氏度)下为157-164 kJ / mol,在高温(800-100摄氏度)下降至58.7-102.1 kJ / mol。在CO2气氛中,NO-CO还原过程中的NO转化率几乎为零,而对于NO炭还原,CO2中的NO转化率低于N-2。但是,CO显示出对NO还原的促进作用。在NO-CO还原过程中,随着CO浓度从0.28%增加到1.88%,NO减少率从0.40增加到0.75。为了减少N-2中的NO-char,引入1%的CO时NO转化率明显更高,并且随着温度的升高,CO的促进作用变弱。此外,在CO 2气氛中抑制了CO的促进作用。

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