electronic Spectroscopy of Aromatic Molecules in Jet-Cooled Hydrogen Bonded Clusters-Structure and Fluxionality

K. Kleinermanns; M. Gerhards; M. Schmitt

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electronic Spectroscopy of Aromatic Molecules in Jet-Cooled Hydrogen Bonded Clusters-Structure and Fluxionality

机译：射流冷却的氢键团簇中芳香分子的电子光谱学-结构和通量

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Spectroscopical and theoretical investigation of various aspects of molecular solvation by hydrogen bonding are presented. The focus in on clusters of phenol with water to study the hydrogen bond in water networks and the solvent interaction with the phenol OH group and the aromatic ring. The phenol dimer and trimer are considered to elucidate the effect of electronic excitation in different cluster moieties. Excited state proton transfer reactions are discussed using clusters of phenol with ammonia as an example.

机译：提出了通过氢键进行分子溶剂化的各个方面的光谱学和理论研究。重点研究苯酚与水的团簇，研究水网络中的氢键以及溶剂与苯酚OH基团和芳环的相互作用。酚二聚体和三聚体被认为可阐明不同簇部分中电子激发的影响。以苯酚与氨的簇为例，讨论了激发态质子转移反应。

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《Berichte der Bunsengesellschaft fur Physikalische Chemie》 |1997年第12期|p.1785-1798|共14页
作者
K. Kleinermanns; M. Gerhards; M. Schmitt;
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正文语种 eng
中图分类化学;
关键词
Clusters; Hydrogen Bonal; Intermolecular Vibrations;

机译：集群;氢硼分子间振动;

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专利

1. Formation of Hydrogen-Bonded Structures in Jet-Cooled Complexes of a Chiral Chromophore Studied by IR/UV Double Resonance Spectroscopy: Diastereoisomeric Complexes of (±)-2-Naphthyl-1-ethanol with (±)-2-Amino-1-propanol [J] . K. Le Barbu, F. Lahmani, A. Zehnacker-Rentien The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第26期

机译：红外/紫外双共振光谱研究手性发色团水冷复合物中氢键结构的形成：（±）-2-萘-1-乙醇与（±）-2-氨基-1-丙醇的非对映异构体
2. Formation of hydrogen-bonded bridgtes in jet-cooled complexes of a chiral chromophore as studied by IR/UV double resonance spectroscopy. (+-)2-Naphthyl-1-ethanol/(methanol)_n = 1,2 complexes [J] . K.Le Barbu-Debus, N.Seurre, F.Lahmani, Physical chemistry chemical physics: PCCP . 2002,第20期

机译：红外/紫外双共振光谱研究表明，手性发色团的射流冷却复合物中氢键键合桥的形成。（+-）2-萘-1-乙醇/（甲醇）_n = 1,2复合物
3. Infrared Spectroscopy of Intramolecular Hydrogen-Bonded OH Stretching Vibrations in Jet-Cooled Methyl Salicylate and Its Clusters [J] . Akira Mitsuzuka, Asuka Fujii, Takayuki Ebata, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第48期

机译：射流冷却的水杨酸甲酯及其簇中分子内氢键合的OH拉伸振动的红外光谱
4. Application of quantum cascade lasers for infrared spectroscopy of jet-cooled molecules and complexes [C] . Yunjie Xu, Xunchen Liu, Zheng Su, Quantum sensing and nanophotonic devices VI . 2009

机译：量子级联激光器在射流冷却的分子和配合物的红外光谱中的应用
5. Electronic spectroscopy of jet-cooled transient triatomic molecules [D] . Sunahori, Fumie Xe 2008

机译：射流冷却的瞬态三原子分子的电子光谱
6. DFT investigation of role of N – H⋯O and N – H⋯π interactions in the stabilization of the hydrogen bonded complexes of anisole with aromatic amines [O] . Anil Singh Rajpurohit, R. Rajesh, R. Raj Muhamed, 2019

机译：DFT研究了N – H⋯O和N – H⋯π相互作用在苯甲醚与芳香胺的氢键配合物的稳定中的作用
7. Shape-Persistent Phenylene-Ethynylene Macrocycles Spectroscopy and Dynamics: From Molecules to the Hydrogen-Bonded Organic Framework Material [O] . Eduardo Gomez, Maria Rosaria di Nunzio, Miquel Moreno, 2020

机译：形状持续亚苯乙烯 - 乙炔基宏ycles光谱和动力学：从分子到氢键合有机骨架材料

electronic Spectroscopy of Aromatic Molecules in Jet-Cooled Hydrogen Bonded Clusters-Structure and Fluxionality

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