Tris-2,2'-Bipyridylruthenium(II) Peroxydisulphate as a Photosensitizer in the Oxidative Degradation of 4-Chlorophenol

M.I. Silva; H.D. Burrows; M. Graca Miguel; S.J. Formosinho

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Tris-2,2'-Bipyridylruthenium(II) Peroxydisulphate as a Photosensitizer in the Oxidative Degradation of 4-Chlorophenol

机译：Tris-2,2'-联吡啶钌（II）过氧二硫酸盐作为光敏剂在4-氯苯酚的氧化降解中的作用

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The photolysis of aerated aqueous solutions of 4-chlorophenol in the presence of Ru(bpy)_3~(2+) and perox-ydisulphate has been followed by UV/visible absorption spectroscopy, and reveals a relatively rapid oxidative decomposition of the phenol. Confirmation of the formation of benzoquinone and dihydroxybenzene as the principal products comes from product separation and spectroscopic characterization, HPLC, and TLC. 4-Chlorocatechol is also produced, while the main inorganic products are shown to be chloride and sulphate ions. Ru(bpy)_3~(2+) is regenerated in the reaction scheme, making this an overall catalytic process. Prolonged irradiation leads to further degradation into CO_2 and HCl. From the study of the kinetics of the reactions and considerations of literature data, a mechanistic scheme is presented.

机译：在Ru（bpy）_3〜（2+）和过氧γ-二硫酸盐存在下，对4-氯苯酚的充气水溶液进行光解后，采用紫外/可见吸收光谱法，发现苯酚的氧化分解相对较快。确认主要产物苯醌和二羟基苯的形成来自产物分离和光谱表征，HPLC和TLC。还生产了4-氯邻苯二酚，而主要的无机产物显示为氯离子和硫酸根离子。 Ru（bpy）_3〜（2+）在反应方案中再生，使其成为整体催化过程。长时间的照射会导致进一步降解为CO_2和HCl。通过对反应动力学的研究和文献数据的考虑，提出了一种机械方案。

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《Berichte der Bunsengesellschaft fur Physikalische Chemie》 |1996年第2期|p.138-143|共6页
作者
M.I. Silva; H.D. Burrows; M. Graca Miguel; S.J. Formosinho;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
organic pollutants; photochemistry; waste treatment;

机译：有机污染物;光化学;废物处理;

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1. Electrogenerated chemiluminescence. 67. Dependence of light emission ofthe tris(2,2 ')bipyridylruthenium(II)/tripropylamine system on electrodesurface hydrophobicity [J] . Zu YB, Bard AJ Analytical chemistry . 2001,第16期

机译：电产生的化学发光。 67.三（2,2'）联吡啶钌（II）/三丙胺体系的发光对电极表面疏水性的依赖性
2. High-throughput method for the analysis of venlafaxine in pharmaceutical formulations and biological fluids, using a tris(2,2′-bipyridyl) ruthenium(II)-peroxydisulphate chemiluminescence system in a two-chip device [J] . Al Lawati H.A.J., Varma G.B., Suliman F.E.O. Luminescence: The journal of biological and chemical luminescence . 2013,第1期

机译：高通量方法，在两芯片设备中使用三（2,2'-联吡啶基）钌（II）-过氧二硫酸盐化学发光系统分析药物制剂和生物流体中的文拉法辛
3. High throughput method for the analysis of cetrizine hydrochloride in pharmaceutical formulations and in biological fluids using a tris(2,2′-bipyridyl)ruthenium(II)-peroxydisulphate chemiluminescence system in a two-chip device [J] . Al Lawati H.A.J., Al Gharibi E., Al Kindy S.M.Z., Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2011,第2期

机译：高通量方法，在两芯片装置中使用三（2,2'-联吡啶基）钌（II）-过二硫酸盐化学发光系统分析药物制剂和生物流体中的盐酸西替利嗪
4. IRON-NICKEL LAYERED DOUBLE HYDROXIDE COMBINED WITH RU(II)-DIIMINE AS VISIBLE LIGHT PHOTOSENSITIZER IN WATER OXIDATION ELECTROCATALYSIS [C] . D. F. Sranko, Zs. E. Horvath, M. Chamam Joint Conference on Chemisty . 2016

机译：铁 - 镍层双氢氧化物与Ru（II）结合Ru（II） - 作为可见光光敏剂在水氧化电催化中
5. The synthesis of mono-substituted disulfide-functionalized 2,2'-bipyridines and the corresponding tris(2,2'-bipyridine)ruthenium(II) complexes for self-assembled monolayers. [D] . Kumpaty, Hephzibah Jayasheela. 1996

机译：用于自组装单层的单取代二硫键官能化的2,2'-联吡啶和相应的三（2,2'-联吡啶）钌（II）配合物的合成。
6. Tris(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III)–(nitrato-κ2OO′)bis(thiocyanato-κN)tris(triphenylphosphine oxide-κO)europium(III) (1/1) [O] . Anthony T. Thames, Frankie D. White, Lam N. Pham, 2012

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7. Reduction of Macrocyclic Cobalt(III) Complex Photosensitized by Tris(2,2′-bipyridine)ruthenium(II) [O] . Yoshimi Kurimura, Emiko Endo 1983

机译：通过Tris（2,2'-Bibyridine）钌（II）感光致敏的宏环钴（III）复合物的减少
8. Heterogeneous Preparation of Singlet Oxygen Using an Ion-Exchange-Resin-Bound Tris(2,2'-bipyridine)-ruthenium(II) Photosensitizer [R] . Buell, S. L., Demas, J. N. 1983

机译：使用离子交换树脂结合的三（2,2'-联吡啶） - 钌（II）光敏剂非均相制备单线态氧

Tris-2,2'-Bipyridylruthenium(II) Peroxydisulphate as a Photosensitizer in the Oxidative Degradation of 4-Chlorophenol

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