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Chemical and Physicochemical Characterization of Alkali Pretreated and in Natura Sisal Solid Waste

机译:碱预处理和Natura Sisal固体废物的化学和物理化学表征

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摘要

Solid waste from sisal fiber is a great candidate for biorefinery feedstock and material for composite production. However, sisal solid waste needs to be pre-treated before being used for such application. One of pretreatment method is chemical pretreatment process using alkaline solution. Alkaline pretreatment can improve the digestibility and physicochemical properties of this lignocellulosic material. The aim of this study was to characterize the in natura and alkali pretreated sisal solid waste in order to evaluate their potential as biorefinery feedstock and material for composite production. The chemical characterization showed that the pretreatment resulted in an increase in cellulose content, which is in agreement with the results of infrared spectra. The DRX pattern and thermal characterization showed a crystallinity degree increase and thermal stability improving, respectively, indicating a partial removal of the amorphous fraction of the lignocellulosic material. The SEM analysis showed that the pretreatment increased the sisal solid waste superficial area, due to extractives removing. These results contributed to elucidate the potential uses of the lignocellulosic material from sisal and how the dilute alkaline pretreatment affected its composition and physicochemical properties.
机译:Sisal纤维的固体废物是用于复合生产的生物遗料原料和材料的伟大候选者。然而,需要预先治疗Sisal固体废物,然后用于这种应用。预处理方法之一是使用碱性溶液的化学预处理方法。碱预处理可以改善这种木质纤维素材料的消化率和物理化学性质。本研究的目的是在Natura和碱预处理的剑麻固体废物中表征,以评估它们作为用于复合生产的生物遗料原料和材料的潜力。化学表征显示预处理导致纤维素含量的增加,这与红外光谱的结果一致。 DRX图案和热表征分别显示出结晶度增加和热稳定性改善,表明木质纤维素材料的非晶部分的部分去除。 SEM分析表明,由于提取物去除,预处理增加了Sisal固体废物浅表面积。这些结果有助于阐明木质纤维素材料与Sisal的潜在用途以及稀释的碱预处理如何影响其组成和物理化学性质。

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