A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions

Annette Svendsen Ulrich J. Lorenz Oleg V. Boyarkin and Thomas R. Rizzo

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A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions

机译：新型串联质谱仪，用于冷气相分子离子的光碎光谱分析

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We present here the design of a new tandem mass spectrometer that combines an electrospray ion source with a cryogenically cooled ion trap for spectroscopic studies of cold, gas-phase ions. The ability to generate large ions in the gas phase without fragmentation, cool them to ∼ 10 K in an ion trap, and perform photofragment spectroscopy opens up new possibilities for spectroscopic characterization of large biomolecular ions. The incorporation of an ion funnel, together with a number of small enhancements, significantly improves the sensitivity, signal stability, and ease of use compared with the previous instrument built in our laboratory. © 2010 American Institute of Physics Article Outline INTRODUCTION INSTRUMENTATION Nanospray source Ion funnel Hexapole ion guide or trap Gate valve Mass selection and octupole ion guide Cryogenic 22-pole ion trap Mass-selected ion detection Electronics EXPERIMENTAL RESULTS Mass spectra and ion currents UV excitation spectrum COMPARISON WITH THE PREVIOUS INSTRUMENT SUMMARY

机译：我们在此介绍一种新型串联质谱仪的设计，该质谱仪将电喷雾离子源与低温冷却离子阱结合在一起，用于冷，气相离子的光谱研究。能够在气相中生成大离子而不会碎裂，在离子阱中将其冷却至〜10 K并进行光碎裂光谱学的能力，为大分子生物分子的光谱表征开辟了新的可能性。与我们实验室中内置的以前的仪器相比，结合使用离子漏斗以及一些小的改进，可以显着提高灵敏度，信号稳定性和易用性。 ©2010美国物理研究所文章大纲简介仪器简介纳米喷雾源离子漏斗六极离子导管或阱闸阀质量选择和八极离子导管低温22极离子阱质量选择的离子检测电子学实验结果质谱和离子流UV激发光谱比较上一个仪器摘要

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来源
《Review of Scientific Instruments》 |2010年第7期|p.1-7|共7页
作者
Annette Svendsen Ulrich J. Lorenz Oleg V. Boyarkin and Thomas R. Rizzo;
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Laboratoire de Chimie Physique Moléculaire, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCPM, Station 6, CH-1015 Lausanne, Switzerland;

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正文语种 eng
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biological techniques; cooling; cryogenics; mass spectra; mass spectroscopy; molecular biophysics;

机译：生物技术;冷却;低温;质谱;质谱;分子生物物理学;

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1. A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions [J] . Svendsen Annette, Lorenz Ulrich J., Boyarkin Oleg V., Review of Scientific Instruments . 2010,第7期

机译：新型串联质谱仪，用于冷气相分子离子的光碎光谱分析
2. Gas-Phase Fragmentation Studies of Biotinylated, Hexaethylene Glycol-Spacered Oligosaccharides-Molecular Probes-Using Electrospray Mass Spectrometry on a Hybrid High-Resolution Mass Spectrometer [J] . Chizhov A. O., Argunov D. A., Gening M. L., Journal of analytical chemistry . 2017,第13期

机译：生物素化，六亚乙二醇 - 脱水剂的气相碎片研究 - 使用电喷雾质谱法在混合高分辨率质谱仪上使用电喷雾质谱法
3. Gas-phase fluorescence excitation and emission spectroscopy of three xanthene dyes (rhodamine 575, rhodamine 590 and rhodamine 6G) in a quadrupole ion trap mass spectrometer [J] . Forbes M.W., Jockusch R.A. Journal of the American Society for Mass Spectrometry . 2011,第1期

机译：四极杆离子阱质谱仪中三种x吨染料（若丹明575，若丹明590和若丹明6G）的气相荧光激发和发射光谱
4. INTEGRATION OF TANDEM MASS SPECTROMETRY MOLECULAR NETWORKING AND GAS-PHASE FRAGMENTATION REACTIONS FOR STRUCTURAL ANALYSIS OF FLAVONOID GLYCOCONJUGATES [C] . Alan Cesar Pilon, Fausto Carnevale Neto, Hawei Gu, International Mass Spectrometry Conference . 2018

机译：串联质谱分子网络与气相碎片反应的整合，对黄酮类化糖缀合物的结构分析
5. Construction and demonstration of a tandem mass spectrometer based instrument for cold ion spectroscopy. [D] . Redwine, James Gerhardt. 2013

机译：基于串联质谱仪的冷离子光谱仪的构建和演示。
6. Gas-Phase Stability of G-quadruplex DNA Determined by Electrospray Ionization Tandem Mass Spectrometry and Molecular Dynamics Simulations [O] . Carolyn L. Mazzitelli, Junmei Wang, Suncerae I. Smith, -1

机译：电喷雾串联质谱法测定G-四链体DNA的气相稳定性和分子动力学模拟
7. Vacuum ultraviolet photochemistry: I. Unimolecular decomposition studies of small hydrocarbon clusters by molecular beam photoionization mass spectrometry; II. Photofragment dynamics study of carbon disulfide by high resolution molecular beam laser photofragment time-of-flight mass spectrometry [O] . Tzeng, Wen-Bih 1986

机译：真空紫外光化学：I.分子束光电离质谱法研究小烃簇的单分子分解；二。高分辨率分子束激光光碎飞行时间质谱研究二硫化碳的光碎动力学
8. Vacuum Ultraviolet Photochemistry. I. Unimolecular Decomposition Studies of Small Hydrocarbon Clusters by Molecular Beam Photoionization Mass Spectrometry; II. Photofragment Dynamics Study of Carbon Disulfide by High Resolution Mo [R] . Tzeng, W. B. 1986

机译：真空紫外光化学。 I.分子束光电离质谱法研究小烃团簇的单分子分解; II。高分辨率mo对二硫化碳的光碎片动力学研究

A new tandem mass spectrometer for photofragment spectroscopy of cold, gas-phase molecular ions

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