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首页> 外文期刊>Review of Scientific Instruments >Increased bandwidth for dielectric spectroscopy of proteins through electrode surface preparation
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Increased bandwidth for dielectric spectroscopy of proteins through electrode surface preparation

机译:通过电极表面制备增加蛋白质介电光谱的带宽

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摘要

Dielectric spectroscopy measurements of liquids are often limited by electrode polarization. The influence of surface polishing and deposition of the conducting polymer polypyrrole/polystyrenesulfonate (PPy/PSS) on the polarization impedance is investigated. A quantitative description of the electrode polarization contribution to the real-valued permittivity spectrum is derived. This description explains the origin of the ω-const. (const.>1) dependency commonly observed in permittivity measurements. Electrode surface roughness is correlated with both the magnitude and phase of the constant phase element. Generally, rougher electrodes have better performance, and an order of magnitude bandwidth improvement is achieved using PPy/PSS electrodes.
机译:液体的介电谱测量通常受电极极化的限制。研究了导电聚合物聚吡咯/聚苯乙烯磺酸盐(PPy / PSS)的表面抛光和沉积对极化阻抗的影响。得出了电极极化对实值介电常数谱的贡献的定量描述。该说明解释了ω -const 的起源。 (常数> 1)介电常数测量中通常观察到的依赖性。电极表面粗糙度与恒定相元素的大小和相位都相关。通常,较粗糙的电极具有更好的性能,并且使用PPy / PSS电极可实现一个数量级的带宽改善。

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