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High‐Resolution NMR Spectrometer with the Radio Frequency Controlled by the Magnetic Field

机译:磁场控制射频的高分辨率NMR光谱仪

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摘要

A practical spectrometer for the observation of high‐resolution proton magnetic resonance spectra at 30 Mc is described. Field modulation is imposed in such a way that ``sideband'' responses are observed, and this enables lock‐in detection to be used, giving increased stability to the baseline of the records. Spectra are displayed by slowly sweeping the modulation frequency and thus are calibrated directly in frequency. The radio‐frequency source is a proton controlled super‐regenerative oscillator, whose frequency follows variations of the electromagnet field. This reduces the effects of field drift and instability, allowing relatively slow scanning speeds to be used in recording the spectra.
机译:描述了一种实用的光谱仪,用于在30 Mc下观察高分辨率质子磁共振谱。进行场调制的方式是观察到``边带''响应,这使得可以使用锁定检测,从而提高了记录基线的稳定性。通过缓慢扫描调制频率来显示频谱,因此可以直接在频率上进行校准。射频源是质子控制的超再生振荡器,其频率遵循电磁场的变化。这减少了场漂移和不稳定性的影响,从而允许在记录光谱时使用相对较低的扫描速度。

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