...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Science of advanced materials >Polyacrylamide/Nafion~® Semi-Interpenetrating Networks as Proton-Conducting Membrane of Direct Methanol Fuel Cell
【24h】

Polyacrylamide/Nafion~® Semi-Interpenetrating Networks as Proton-Conducting Membrane of Direct Methanol Fuel Cell

机译：聚丙烯酰胺/ Nafion〜®半互穿网络作为直接甲醇燃料电池的质子传导膜

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Direct methanol fuel cells (DMFCs) technology is considered promising for green and efficient power generation. However, a major limitation of DMFCs is methanol crossover from the anode to the cathode. Herein, a phosphoric acid-imbibed polyacrylamide (PAM)/Nafion~® composite membrane, a semi-interpenetrating polymer network was investigated for its potential use as an efficient proton exchange membrane for DMFC application. The extraordinary ability of the PAM/Nafion~® composite membrane to absorb a large quantity of aqueous solution was exploited to achieve a high phosphoric acid loading, for the generation of membranes with high proton conductivity. The PAM/Nafion~® composite membrane also exhibited excellent acid retention and high humidity with a comparatively low methanol crossover, which are very important prerequisites for the DMFC application. The surface morphologies and cross-section of the prepared PAM/Nafion~® composite membrane were observed via optical microscopy and scanning electron microscopy (SEM). Thermogravimetric analysis (TGA) demonstrated improved thermal properties of the prepared membranes. Based on performance, in conjunction with the low-cost synthesis approach, the new membrane was deemed feasible for use in DMFCs.
机译：直接甲醇燃料电池（DMFC）技术被认为有望实现绿色高效发电。然而，DMFC的主要限制是甲醇从阳极到阴极的穿越。在本文中，研究了一种磷酸吸收的聚丙烯酰胺（PAM）/Nafion®复合膜（一种半互穿聚合物网络）作为潜在的DMFC应用质子交换膜的潜在用途。利用PAM / Nafion〜®复合膜吸收大量水溶液的非凡能力来实现高磷酸负载，从而生成具有高质子传导性的膜。 PAM / Nafion〜®复合膜还表现出优异的耐酸性和高湿度，甲醇穿透率较低，这是DMFC应用的重要先决条件。通过光学显微镜和扫描电子显微镜（SEM）观察制备的PAM / Nafion？复合膜的表面形态和横截面。热重分析（TGA）表明，所制备的膜的热性能有所改善。基于性能，结合低成本合成方法，该新型膜被认为可用于DMFC。

著录项

  • 来源
    《Science of advanced materials》 |2014年第11期|2389-2394|共6页
  • 作者

    Krishan Talukdar; Hee Jin Kim; Young Ho Kim; Ho-Chang Lee; Sang-June Choi;

  • 作者单位

    Department of Environmental Engineering, Kyungpook National University, Daegu 702-701, Korea;

    Research Institute of Advanced Energy Technology, Kyungpook National University, Daegu 702-701, Korea;

    Research Institute of Advanced Energy Technology, Kyungpook National University, Daegu 702-701, Korea ,Medical Device Development Center, Daegu-Gyeongbuk Medical Innovation Foundation, Daegu 706-010, Korea;

    School of Materials Science and Engineering, Kyungpook National University, Daegu 702-701, Korea;

    Department of Environmental Engineering, Kyungpook National University, Daegu 702-701, Korea ,Research Institute of Advanced Energy Technology, Kyungpook National University, Daegu 702-701, Korea;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Polymer Electrolytes; Polymer Electrolyte Membrane Fuel Cell (PEMFC); Ionic Exchange Membrane; Semi-Interpenetrating Network;

    机译：高分子电解质;聚合物电解质膜燃料电池（PEMFC）;离子交换膜半互穿网络;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号