Comparison between different reactions of group IV hydride with H

ZHANG Shaolong; ZHANG Xuqiang; ZHANG Qinggang; ZHANG Yici

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Comparison between different reactions of group IV hydride with H

机译：IV族氢化物与H的不同反应之间的比较

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The four-dimensional time-dependent quantum dynamics calculations for reactions of group IV hydride with H are carried out by employing the semirigid vibrating rotor target model and the time-dependent wave packet method. The reaction possibility, cross section and rate constants for reactions (H+SiH_4 and H+GeH_4) in different initial vibrational and rotational states are obtained. The common feature for such kind of reaction process is summarized. The theoretical result is consistent with available measurement, which indicates the credibility of this theory and the potential energy surface.

机译：采用半刚性振动转子目标模型和时变波包方法，对IV族氢化物与H的反应进行了时空四维量子动力学计算。获得了在不同的初始振动和旋转状态下反应的反应可能性，截面和速率常数（H + SiH_4和H + GeH_4）。总结了这种反应过程的共同特点。理论结果与可用的测量结果一致，表明该理论和势能面的可信度。

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来源
《Science in China. Series G, Physics, Mechanics & Astronomy》 |2006年第4期|p.496-504|共9页
作者
ZHANG Shaolong; ZHANG Xuqiang; ZHANG Qinggang; ZHANG Yici;
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作者单位

College of Physics and Electronics, Shandong Normal University, Jinan 250014, China;

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原文格式 PDF
正文语种 eng
中图分类自然科学总论;
关键词
SVRT mode; time-dependent wave packet; reaction probability; rate constant;

机译：SVRT模式;时变波包;反应概率;速率常数;

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1. Comparison between different reactions of group IV hydride with H [J] . ZHANG Shaolong, ZHANG Xuqiang, ZHANG Qinggang, 中国科学:物理学力学天文学（英文版） . 2006,第004期

机译：与H组硫化物族不同反应的比较
2. Hydrogen Atom and Hydride Transfer in the Reactions of Chromium (IV) and Chromium(V) Complexes with Rhodium Hydrides. Crystal Structure of a Superoxorhodium(III) Product [J] . Bakac Andreja, Guzei Ilia A. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第4期

机译：铬（IV）和铬（V）配合物与氢化铑反应中的氢原子和氢化物转移。 Superoxorhodium（III）产品的晶体结构
3. Hydrogen Atom and Hydride Transfer in the Reactions of Chromium (IV) and Chromium(V) Complexes with Rhodium Hydrides. Crystal Structure of a Superoxorhodium(III) Product [J] . Bakac Andreja, Guzei Ilia A. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第4期

机译：铬（IV）和铬（V）配合物与氢化铑反应中的氢原子和氢化物转移。 Superoxorhodium（III）产品的晶体结构
4. Thermodynamic Investigation of Titanium Hydride Formation from Reduction of Titanium (IV) Chloride with Magnesium Hydride in Presence of Hydrogen Atmosphere [C] . Mohammad Rezaei Ardani, Ahmad Fauzi Mohd Noor, Sheikh Abdul Rezan Sheikh Abdul Hamid World Conference on Titanium . 2020

机译：氢化镁在氢气存在下用氢化镁的钛（IV）氯化钛的热力学研究
5. Molybdenum (IV) imido silylamido and hydride complexes: Stoichiometric and catalytic reactivity, mechanistic aspects of hydrosilation reactions. [D] . Khalimon, Andrey Y. 2010

机译：钼（IV）亚氨基甲硅烷基和氢化物配合物：化学计量和催化反应性，硅氢化反应的机理。
6. Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides [O] . Dionisio Poveda, Ángela Vivancos, Delia Bautista, 2020

机译：可见光驱动的发电和稳定双环级稳定的Pt（iv）氢化物的炔烃插入反应
7. Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides [O] . Dionisio Poveda, Ángela Vivancos, Delia Bautista, 2020

机译：可见光驱动的发电和稳定双环级稳定的Pt（iv）氢化物的炔烃插入反应
8. Addition Compounds of Alkali Metal Hydrides. 13. Reactions of Alkali Metal Hydrides with Trialkylboranes. Synthesis and Dissociation of Alkali Metal Trialkylborohydrides. Ethyl Ether-Organoborane as a Reversible 'Solvent' for Lithium Hydride. [R] . Brown, H. C., Khuri, A., Kim, S. C. 1977

机译：碱金属氢化物的加成化合物。 13.碱金属氢化物与三烷基硼烷的反应。碱金属三烷基硼氢化物的合成与解离。乙醚 - 有机硼烷作为氢化锂的可逆“溶剂”。

Comparison between different reactions of group IV hydride with H

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