INTERMOLECULAR INTERACTIONS OF AMINO ACIDS IN AQUEOUS KNO_3 SOLUTION AT 303, 308 AND 313 K

R. PALANI; L. R. ESWARI; R. KESAVASAMY

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INTERMOLECULAR INTERACTIONS OF AMINO ACIDS IN AQUEOUS KNO_3 SOLUTION AT 303, 308 AND 313 K

机译：氨基酸在303、308和313 K时在KNO_3水溶液中的分子间相互作用

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Density (ρ), viscosity (η) and ultrasonic velocity (U) have been measured for glycine, L-alanine and L-serine in aqueous KNO_3 solution (1 mol·kg~(-1)) at 303, 308 and 313 K. Using these data adiabatic compressibility (p), hydration number (n_H), apparent molal compressibilityrn(φ_K), apparent molal volume (φ_V), limiting apparent molalrncompressibility (φ_K~0 ), limiting apparent molal volume (φ_V~0)rnand their constants (S_K, S_V) and B-coefficients of Jones-Dole equation were calculated. The results of these parameters have been discussed in terms of ion-solvent and ion-ion interactions operative in the systems.

机译：在303、308和313 K下，测定了KNO_3水溶液（1 mol·kg〜（-1））中甘氨酸，L-丙氨酸和L-丝氨酸的密度（ρ），粘度（η）和超声速度（U）。利用这些数据绝热压缩率（p），水合数（n_H），表观摩尔压缩率rn（φ_K），表观摩尔体积（φ_V），极限表观摩尔压缩率（φ_K〜0），极限表观摩尔体积（φ_V〜0）rn及其计算Jones-Dole方程的常数（S_K，S_V）和B系数。这些参数的结果已根据系统中有效的离子溶剂和离子-离子相互作用进行了讨论。

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来源
《Acta Ciencia Indica》 |2009年第4期|p.593-600|共8页
作者
R. PALANI; L. R. ESWARI; R. KESAVASAMY;
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作者单位

Department of Physics, D.D.E., Annamalai University, Annamalainagar - 608 002 (T.N.), India;

Department of Physics, D.D.E., Annamalai University, Annamalainagar - 608 002 (T.N.), India;

Department of Physics, Sri Ramakrishna Engineering College, Coimbatore-641 022 (T.N.), India;

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正文语种 eng
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ultrasonic velocity; adiabatic compressibility; apparent moial volume; hydration number;

机译：超声波速度绝热可压缩性表观mo量水化数;

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4. 13 C NMR Spectroscopic Studies of Intra- and Intermolecular Interactions of Amino Acid Derivatives in Solutions [C] . Yoshikazu Hiraga, Yuri Uyama, Ryosuke Hoshide 日本化学会春季年会講演予稿集 . 2018

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5. Conformations of Some Amino Acids in Aqueous Solutions by Vibrational Circular Dichroism Spectroscopy. [D] . Zhu, PeiYan. 2012

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INTERMOLECULAR INTERACTIONS OF AMINO ACIDS IN AQUEOUS KNO_3 SOLUTION AT 303, 308 AND 313 K

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