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首页> 外文期刊>Sensors and Actuators >An innovative gas sensor system designed from a sensitive organic semiconductor downstream a nanocarbonaceous chemical filter for the selective detection of NO_2 in an environmental context Part I: Development of a nanocarbon filter for the removal of ozone
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An innovative gas sensor system designed from a sensitive organic semiconductor downstream a nanocarbonaceous chemical filter for the selective detection of NO_2 in an environmental context Part I: Development of a nanocarbon filter for the removal of ozone

机译:一种创新的气体传感器系统,由纳米碳质化学过滤器下游的敏感有机半导体构成,用于在环境中选择性检测NO_2第一部分:开发用于去除臭氧的纳米碳过滤器

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摘要

An original gas sensor system dedicated to the selective monitoring of nitrogen dioxide in air has been successfully developed. This device combines the great sensitivity and the partial selectivity toward oxidizing gases of a molecular organic semiconductor, copper phthalocyanine, with the O_3 filtering capability of different carbonaceous nanomaterials located upstream the sensitive layer in the gas flux. The carbonaceous materials are used either as-prepared or modified by physical or chemical treatments. The ability to filter nitrogen dioxide and ozone, has been correlated to both the BET specific surface area determined by N_2 adsorption at 77 K and the presence of chemical functional groups at the surface. A sensing structure is finally proposed using a chemical filter containing nanocarbons, impermeable to ozone and inert toward nitrogen dioxide, leading to a selective NO_2 sensor response.
机译:专门用于选择性监测空气中二氧化氮的原始气体传感器系统已经成功开发。该装置结合了分子有机半导体铜酞菁对氧化性气体的高灵敏度和部分选择性,以及在气体通量中位于敏感层上游的不同碳纳米材料的O_3过滤能力。含碳材料可以直接使用,也可以通过物理或化学处理进行改性。过滤二氧化氮和臭氧的能力已经与通过在77 K处的N_2吸附确定的BET比表面积和表面化学官能团的存在相关。最终提出了一种使用含有纳米碳的化学过滤器的感应结构,该碳纳米管不渗透臭氧并且对二氧化氮呈惰性,从而导致选择性的NO_2传感器响应。

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  • 来源
    《Sensors and Actuators》 |2012年第2012期|p.659-667|共9页
  • 作者单位

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal. Institut de Chimie de Clermont-Ferrand, BP 10448. F-63000 Clermont-Ferrand, France,CNRS. UMR6002. Institut de Chimiede Clermont-Ferrand, F-63177 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France,Clermont Universite, Universite Blaise Pascal. Institut de Chimie de Clermont-Ferrand, BP 10448. F-63000 Clermont-Ferrand, France,CNRS. UMR6002. Institut de Chimiede Clermont-Ferrand, F-63177 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France,Clermont Universite, Universite Blaise Pascal. Institut de Chimie de Clermont-Ferrand, BP 10448. F-63000 Clermont-Ferrand, France,CNRS. UMR6002. Institut de Chimiede Clermont-Ferrand, F-63177 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal. Institut de Chimie de Clermont-Ferrand, BP 10448. F-63000 Clermont-Ferrand, France,CNRS. UMR6002. Institut de Chimiede Clermont-Ferrand, F-63177 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France;

    Clermont Universite, Universite Blaise Pascal, Institut Pascal, BP 10448, F-63000 Clermont-Ferrand, France,CNRS, UMR 6602. Institut Pascal. F-63171 Aubiere, France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    gas sensor; selectivity; filter; organic semiconductor; nanocarbon NO_2;

    机译:气体传感器选择性过滤;有机半导体纳米碳NO_2;

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