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Preparation, characterization and gas-sensing properties of rare earth mixed oxides

机译:稀土混合氧化物的制备,表征和气敏性能

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摘要

Nanometer materials of rare earth mixed oxides REFeO_3 (RE = Eu, Gd) with the structure of perovskite type were synthesized by sol-gel method in the citric acid system. The structure and crystal phase of the powders were characterized on an X-ray diffractometer. The shape and size were analyzed with the help of JEM-100X Transmission electron microscopy. The results show that the morphologies of the two perovskite-type oxides are spherical with the mean grain size of 20 and 21 nm, respectively. Their crystal structures show a certain amount of lattice distortion due to the decrease of grain size and the increase of surface area. Gas sensitivities of these two kinds of materials to C_2H_5OH, H_2S, gasoline and H_2 were tested. The studies of gas-sensing characteristics show the sensitivities of EuFeO_3 and GdFeO_3 nanometer materials to gasoline are 39 and 45 at 340 ℃, respectively, and both of them have appropriate selectivity. So they are promising candidates for the detection of gasoline in monitoring environment.
机译:通过溶胶-凝胶法在柠檬酸体系中合成了钙钛矿型结构的稀土混合氧化物REFeO_3(RE = Eu,Gd)纳米材料。用X射线衍射仪表征粉末的结构和晶相。借助于JEM-100X透射电子显微镜分析其形状和尺寸。结果表明,两种钙钛矿型氧化物的形态均为球形,平均粒径分别为20和21 nm。由于晶粒尺寸的减小和表面积的增加,它们的晶体结构表现出一定量的晶格畸变。测试了这两种材料对C_2H_5OH,H_2S,汽油和H_2的气体敏感性。气敏特性的研究表明,EuFeO_3和GdFeO_3纳米材料在340℃下对汽油的敏感性分别为39和45,并且两者都具有适当的选择性。因此,它们是在监测环境中检测汽油的有希望的候选人。

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