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首页> 外文期刊>Sensors Journal, IEEE >Optical Properties and Swelling Behavior of Fe3O4 Functionalized Graphene Oxide Composite Thin Film
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Optical Properties and Swelling Behavior of Fe3O4 Functionalized Graphene Oxide Composite Thin Film

机译:Fe3O4功能化氧化石墨烯复合薄膜的光学性质和溶胀行为

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The optical characterization and gas sensing properties of Fe3O4 functionalized graphene oxide (GO) composite [Fe3O4-(3-aminopropyl)triethoxysilane GO (APTES-GO)] thin film are discussed in this paper by using spin coating, UV-visible spectroscopy, transmission electron microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction measurements, Surface Plasmon Resonance, and quartz crystal microbalance (QCM) techniques. The Fe3O4-APTES-GO thin films with thickness in the range between 14 and 31 nm have been successfully prepared, when films were spun at speeds between 1000 and 4000 rpm with a refractive index values of between 1.32 and 1.37. In this paper, the swelling behaviors of the Fe3O4-APTES-GO thin films were investigated with respect to volatile organic compounds (VOCs) at room temperature by using the QCM method. The swelling processes could be investigated using the early-time Fick’s law of diffusion. Diffusion coefficients were found to be 24.17times 10^{mathrm {mathbf {-16}}} , 13.99times 10^{mathrm {mathbf {-16}}} , 3.97times 10^{mathrm {mathbf {-16}}} , and 1.73times 10^{mathrm {mathbf {-16}}} cm2 text{s}^{mathrm {mathbf {-1}}} for dichloromethane, chloroform, benzene, and toluene vapors, respectively. The response of the Fe3O4-APTES-GO films to the these VOCs has been investigated in the conditions of physical properties of the solvents, and the films were obtained to be largely sensitive to dichloromethane and chloroform vapors compared with other studied vapors.
机译:本文通过旋涂,紫外可见光谱,透射光谱等研究了Fe3O4功能化氧化石墨(GO)复合[Fe3O4-(3-氨基丙基)三乙氧基硅烷GO(APTES-GO)]薄膜的光学表征和气敏特性。电子显微镜,扫描电子显微镜,能量色散X射线光谱仪,X射线衍射测量,表面等离子体共振和石英晶体微量天平(QCM)技术。 Fe3O4-APTES-GO薄膜的厚度在14到31 nm之间时,已经成功制备,当薄膜以1000到4000 rpm的速度旋转时,其折射率值在1.32到1.37之间。本文采用QCM方法研究了Fe3O4-APTES-GO薄膜在室温下相对于挥发性有机化合物(VOC)的溶胀行为。可以使用早期的Fick扩散定律研究膨胀过程。发现扩散系数为24.17乘以10 ^ {mathrm {mathbf {-16}}},13.99乘以10 ^ {mathrm {mathbf {-16}}},3.97乘以10 ^ {mathrm {mathbf {-16}}} ,分别是二氯甲烷,氯仿,苯和甲苯蒸气的10 ^ {mathrm {mathbf {-16}}} cm2文本{s} ^ {mathrm {mathbf {-1}}} cm2。已经在溶剂的物理性质条件下研究了Fe3O4-APTES-GO膜对这些VOC的响应,并且与其他研究的蒸气相比,获得的膜对二氯甲烷和氯仿蒸气非常敏感。

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    《Sensors Journal, IEEE》 |2017年第5期|1222-1229|共8页
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