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Hydrofining of the Overhead Products of the Liquefaction of Coal from the Mamytskoe Deposit

机译:Mamytskoe矿床煤液化塔顶产物的加氢精制

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摘要

The hydrogenation process of coal distillates with bp 180-360 degrees C in the presence of Mo- and Co-containing catalysts supported on the surface of skeletal nickel (Raney Ni) was studied. It was established that, in the presence of a catalyst containing 5% Mo/Ni-Re + 7% Co/Ni-Re at a pressure of 10 MPa, a temperature of 400 degrees C, and a feed space velocity of 1.0 h(-1), phenols and nitrogen bases were completely removed; sulfur and unsaturated compounds were hydrogenated by 95.4 and 94.7%, respectively; and aromatic hydrocarbons were hydrogenated by 69.7%. The hydrofined distillate fractions with bp 180-360 degrees C meet the requirements of GOST [State Standard] R 52368-2005 (Russia) and the EN 590-2004 EU standard for low-sulfur diesel fuel in terms of their physicochemical and operational properties, and hydrotreated gasoline can be used as a component of low-octane gasoline.
机译:研究了在骨架镍(阮内镍)表面负载的含钼和钴的催化剂的存在下,沸点为180-360℃的煤馏分的加氢过程。已确定在压力为10 MPa,温度为400摄氏度,进料空速为1.0小时的条件下,在含有5%Mo / Ni-Re + 7%Co / Ni-Re的催化剂的存在下( -1),苯酚和氮碱被完全除去;硫和不饱和化合物分别氢化了95.4和94.7%;芳香烃的氢化率为69.7%。沸点为180-360摄氏度的加氢精制馏分在物理化学和操作性能方面均符合GOST [国家标准] R 52368-2005(俄罗斯)和EN 590-2004欧盟低硫柴油标准的要求,加氢处理汽油可用作低辛烷值汽油的成分。

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