KINETICS OF THE DEGRADATION OF HUMIC ACIDS

N.V. Chukhareva; L.V. Shishmina; A.A. Novikov

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KINETICS OF THE DEGRADATION OF HUMIC ACIDS

机译：腐殖酸降解的动力学

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Processes of thermal decarboxylation and dehydration of humic acids are represented by a sum of independent first-order reactions, which are characterized by certain kinetic parameters. The authors estimated the effect of preheating of peat on the change in the total contribution of identified reactions in the temperature ranges 100-250, 250-450 and 450-800℃. A probable chemical structure of reactions sites is proposed.

机译：腐殖酸的热脱羧和脱水过程由独立的一级反应的总和表示，这些一级反应以某些动力学参数为特征。作者估计了在100-250、250-450和450-800℃的温度下，泥炭的预热对已确定反应的总贡献变化的影响。提出了反应部位可能的化学结构。

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《Solid Fuel Chemistry》 |2003年第6期|p.30-41|共12页
作者
N.V. Chukhareva; L.V. Shishmina; A.A. Novikov;
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作者单位

Tomsk Polytechnic University;

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正文语种 eng
中图分类燃料化学工业（总论）;
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2. The kinetics of thermo-oxidative humic acids degradation studied by isoconversional methods [J] . D. Válková, J. Kislinger, M. Pekař, Journal of Thermal Analysis and Calorimetry . 2007,第3期

机译：等转化法研究热氧化腐殖酸降解动力学
3. The kinetics of thermo-oxidative humic acids degradation studied by isoconversional methods [J] . Valkova D, Kislinger J, Pekar M, Journal of thermal analysis and calorimetry . 2007,第3期

机译：等转化法研究热氧化腐殖酸降解动力学
4. THERMAL DEGRADATION KINETICS PARAMETERS OF HUMIC ACIDS WHEN FREE AND ANCHORED ONTO SILICA GEL SURFACE [C] . Elaine A.Faria, Barbara S.Miranda, Paolla C.Martins, International Meeting of IHSS . 2004

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5. Photochemical reduction of divalent mercury (Hg(II)) in UVB light by humic acids and low molecular mass organic acids (oxalate, cysteine): A probe into mechanism and kinetics. [D] . Okine, Stephen Kojo. 2013

机译：腐殖酸和低分子量有机酸（草酸盐，半胱氨酸）对UVB光中二价汞（Hg（II））的光化学还原：机理和动力学的探讨。
6. Soil humic acids degrade CWD prions and reduce infectivity [O] . Alsu Kuznetsova, Catherine Cullingham, Debbie McKenzie, 2018

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7. Humic Acids Degradation by a Hybrid Photocatalysis-Membrane Process: Effect of UV-A Photon dose on Mineralization Kinetics [O] . Sarasidis V.C., Patsios S.I., Karabelas A.J. 2012

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8. Experimental investigation of aqueous corrosion of R7T7 nuclear glass at 90 deg C in the presence of humic acids: a kinetic approach [R] . Gin, S. , Godon, N. , Mestre, J. P. , 1993

机译：R9T7核玻璃在腐殖酸存在下在90℃水溶液腐蚀的实验研究：动力学方法

KINETICS OF THE DEGRADATION OF HUMIC ACIDS

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