RELATION BETWEEN THE DEGREE OF THERMAL LIQUEFACTION OF MOSCOW BASIN BROWN COALS AND THE STRUCTURE AND CONTENT OF PHENOLS IN LOW-TEMPERATURE CARBONIZATION TAR

V.V. Platonov; V.A. Proskuryakov; V.E. Savchenkov

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RELATION BETWEEN THE DEGREE OF THERMAL LIQUEFACTION OF MOSCOW BASIN BROWN COALS AND THE STRUCTURE AND CONTENT OF PHENOLS IN LOW-TEMPERATURE CARBONIZATION TAR

机译：低温碳化焦油中莫斯科盆地棕色煤的热液化程度与酚的结构和含量之间的关系

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The methods of elemental, functional, structural-group analysis, IR, UV, and H-NMR spectroscopies, capillary gas chromatography, and cryoscopy were used To study in detail the chemical composition of phenols in the tars of low-temperature Carbonization of Moscow Basin brown coals. We found that the phenols are an Involved mixture of high-molecular compounds that in addition to the phenol groups Contain alcohol, ketone, and alkoxyl groups, quinoid rings, oxygen in the composition Of the heterocycles, therefore they can be called phenols only conditionally. We Also found that the degree of liquefaction of the organic matter of the coals Correlates positively with the content in the low-temperature carbonization tar of di- and triatomic phenols, their ethers, indanols, cresols, and xylenols.

机译：使用了元素，功能，结构基团分析，IR，UV和H-NMR光谱，毛细管气相色谱和低温显微镜的方法来详细研究莫斯科盆地低温碳化过程中焦油中酚的化学组成褐煤。我们发现酚是高分子化合物的涉入混合物，除了酚基团在杂环的组成中还包含醇，酮和烷氧基，喹啉环，氧，因此它们只能在有条件的情况下称为酚。我们还发现，煤中有机物的液化程度与二和三原子酚，其醚，茚满醇，甲酚和二甲苯酚的低温碳化焦油含量成正相关。

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《Solid Fuel Chemistry》 |2000年第1期|p.83-91|共9页
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V.V. Platonov; V.A. Proskuryakov; V.E. Savchenkov;
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中图分类燃料化学工业（总论）;
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RELATION BETWEEN THE DEGREE OF THERMAL LIQUEFACTION OF MOSCOW BASIN BROWN COALS AND THE STRUCTURE AND CONTENT OF PHENOLS IN LOW-TEMPERATURE CARBONIZATION TAR

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