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首页> 外文期刊>Solid Fuel Chemistry >FEATURES OF ADSORPTION AND EQUILIBRIUM IN THE COMPLETE COMBUSTION OF CARBON IN A CLOSED SPACE
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FEATURES OF ADSORPTION AND EQUILIBRIUM IN THE COMPLETE COMBUSTION OF CARBON IN A CLOSED SPACE

机译：封闭空间内碳完全燃烧的吸附和平衡特征

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The relation between adsorption and chemical transformation is studied when the reaction of complete combustion o carbon proceeds in a closed space. With such a formulation of the problem, the behavior of the system is described by five mutually related nonlinear differential equations of the first order. It is shown that depending on the ratio of the initial pressures of the O_2 and CO_2, the system in time may either arrive at an equilibrium state, or asymptotic attenuation of the intensity of the reaction will be observed in it in connection with the complete consumption of the solid carbon. Arriving at equilibrium is ensured within a broad range of the change in the ratio of the CO_2 pressure to that of the O_2. It is shown that after an equilibrium state is reached, the parameters of the system will satisfy the five requirements. On these grounds, we obtained the equilibrium contents of all the components in the system and determined the relevant adsorption isotherms.
机译：当完全燃烧或碳在密闭空间中进行反应时，研究了吸附与化学转化之间的关系。通过这样的问题表述，系统的行为由五个相互关联的一阶非线性微分方程描述。结果表明，根据O_2和CO_2初始压力的比值，系统可能会及时达到平衡状态，或者在完全消耗的情况下观察到反应强度的渐近衰减。固体碳。确保在CO_2压力与O_2压力之比的变化范围很大的范围内达到平衡。结果表明，达到平衡状态后，系统参数将满足五个要求。基于这些理由，我们获得了系统中所有组分的平衡含量，并确定了相关的吸附等温线。

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