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Temperature-modulated scanning tunneling spectroscopy of gold nanoparticle dropcast films

机译:金纳米粒子压铸薄膜的温度调制扫描隧道光谱

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The electronic conductivity of a gold nanoparticle dropcast film was examined by temperature-modulated scanning tunneling spectroscopy (STS). The low-conductance Coulomb blockade was found to shrink with increasing temperature, which at ambient temperature (ca. 290 K) diminished completely. Concomitantly, the potential spacing between adjacent peaks observed in the Coulomb staircase features exhibited a marked increase at approximately the same temperature. Both observations suggest an enhancement of the particle film electronic conductivity with increasing temperature. Such a transition was ascribed to the combined consequence of thermal activation of interparticle charge transfer and particle coherent thermal motions.
机译:通过温度调制扫描隧道光谱法(STS)检查了金纳米颗粒滴铸膜的电子电导率。人们发现,随着温度的升高,低电导的库仑阻塞会缩小,在环境温度(约290 K)下,这种阻塞会完全消失。因此,在大约相同的温度下,在库伦阶梯特征中观察到的相邻峰之间的电位间隔显示出明显的增加。两种观察结果都表明,随着温度的升高,颗粒膜的电导率增加。这种转变归因于粒子间电荷转移的热活化和粒子相干热运动的综合结果。

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