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Measurements of the heat capacity of diamond with different isotopic compositions

机译:不同同位素组成的金刚石的热容测量

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We report measurements of the heat capacity C,, of diamond with several isotopic compositions (C-12(1-x) C-13(x)) in the 20 - 280 K temperature range. The results, in particular the derivative of the specific heat with respect to the average isotopic mass, are compared with recent ab initio calculations. Agreement is good for T > 150 K. At lower temperatures, the samples with isotopic compositions different from the natural one display an anomalous increase in C-rho/T-3 with decreasing temperature which is attributed to the presence of metallic inclusions stemming from the metal used as a solvent in the high-pressure high-temperature growth process. (C) 2004 Elsevier Ltd. All rights reserved.
机译:我们报告了在20-280 K温度范围内具有几种同位素组成(C-12(1-x)C-13(x))的金刚石的热容C i的测量值。将结果,特别是比热相对于平均同位素质量的导数,与最近的从头算计算进行了比较。协议适用于T> 150K。在较低的温度下,同位素组成与天然样品不同的样品随温度降低显示C-rho / T-3异常增加,这归因于金属夹杂物的存在。在高压高温生长过程中用作溶剂的金属。 (C)2004 Elsevier Ltd.保留所有权利。

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