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Scalable synthesis of Sb(Ⅲ)Sb(Ⅴ)O_4 nanorods from Sb_2O_5 powder via solvothermal processing

机译:溶剂热法从Sb_2O_5粉末可扩展合成Sb(Ⅲ)Sb(Ⅴ)O_4纳米棒

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摘要

Scalable Sb(Ⅲ)Sb(Ⅴ)O_4 nanorods from Sb_2O_5 powder were prepared using solvothermal route. XRD and HRTEM demonstrate that the nanorods are single-crystal orthorhombic-Sb_2O_4 phase with several micrometers long and 200-300 nm diameter size. XPS result further shows that the antimony cations in the nanorods are composed of three valence and five valence antimony ions. The emission of the nanorods appears around 450 nm wavelength. The formation mechanism of the Sb(Ⅲ)Sb(Ⅴ)O_4 nanorods was discussed in detail.
机译:采用溶剂热法从Sb_2O_5粉末中制备出可扩展的Sb(Ⅲ)Sb(Ⅴ)O_4纳米棒。 XRD和HRTEM证明纳米棒为单晶正交的Sb_2O_4相,长度为几微米,直径为200-300 nm。 XPS结果进一步表明,纳米棒中的锑阳离子由三价和五价锑离子组成。纳米棒的发射出现在450 nm波长附近。详细讨论了Sb(Ⅲ)Sb(Ⅴ)O_4纳米棒的形成机理。

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