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Effect of Ti doping on the electrical transport and magnetic properties of layered compound Na_(0.8)CoO_2

机译:Ti掺杂对层状化合物Na_(0.8)CoO_2的电输运和磁性能的影响

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摘要

Effect of Ti doping on the electrical transport and magnetic properties of layered Na_(0.8)CO_(1-x)Ti_xO_2 compounds has been investigated. The lattice parameters a and c increase with x. A minor amount of Ti doping results in a metal-insulator transition at low temperatures. For samples with x>0.03, the variable-range hopping process dominates the transport behavior above a certain temperature. The temperature dependence of magnetization of all the samples is found to obey the Curie-Weiss law. The mechanism of the doping effect is discussed.
机译:研究了Ti掺杂对层状Na_(0.8)CO_(1-x)Ti_xO_2化合物的电输运和磁性能的影响。晶格参数a和c随着x增大。少量的Ti掺杂会导致低温下的金属-绝缘体转变。对于x> 0.03的样品,在一定温度以上,可变范围跳跃过程决定了传输行为。发现所有样品的磁化强度对温度的依赖性都服从居里-魏斯定律。讨论了掺杂效应的机理。

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