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Magnetic moments of small hydrogen clusters

机译:小氢簇的磁矩

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Molecular beams of small normal hydrogen (nH(2)) clusters (N approximate to 20) produced in a low temperature free jet expansion are investigated for their magnetic properties by deflecting them in an inhomogeneous Stern-Gerlach type magnetic field. The mass distributions of the clusters are measured by diffraction from a nano-structured transmission grating. With their masses known the Gaussian shaped symmetric deflection patterns of the pure nH2 clusters can be simulated by a random distribution of both the nuclear and rotational magnetic moments of the 75% ortho J = 1 component. Upon cooling the nH(2) clusters to below I K by expanding a mixture of 5% nH(2) in 95% He-4 gas the deflection pattern is split into three central peaks. This observation is consistent with a partial orientational ordering of the ortho H-2 molecules leading to a reduction of the total rotational magnetic moments of the clusters. (C) 2004 Elsevier Ltd. All rights reserved.
机译:通过在不均匀的斯特恩-盖拉赫(Stern-Gerlach)型磁场中偏转分子束,研究了在低温自由射流膨胀下产生的小常规氢分子束(nH(2))(N约为20)的磁性能。团簇的质量分布通过来自纳米结构的透射光栅的衍射来测量。利用已知的质量,可以通过75%正交J = 1分量的核磁矩和旋转磁矩的随机分布来模拟纯nH2团簇的高斯形状对称偏转模式。通过将5%nH(2)在95%He-4气体中的混合物膨胀,将nH(2)团簇冷却至I K以下时,偏转模式分为三个中心峰。该观察结果与邻H-2分子的部分取向顺序一致,导致簇的总旋转磁矩减少。 (C)2004 Elsevier Ltd.保留所有权利。

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