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New conducting thin films derived from M(dimt)_2 salts (M = Ni(Ⅱ), Pd(Ⅱ)) by using poly counter cations

机译:利用聚抗衡阳离子从M(dimt)_2盐(M = Ni(Ⅱ),Pd(Ⅱ))衍生的新型导电薄膜

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摘要

Two kinds of new M(dmit)_2 salts (M = Ni and Pd, (dmit = 1,3-dithole-2-thione-4,5-dithiolate)) containing poly(4-vinyl-N-octanylpyridinium) (PVOP) as counter cations were synthesized. Semiconducting thin films derived from these salts were prepared by electrochemical deposition method. The Ni(dmit)_2 film shows an extremely smooth and uniform surface. The film-forming property of the Ni(dmit)_2 salt has been improved significantly by using PVOP as counter cation.
机译:含聚(4-乙烯基-N-辛基吡啶鎓)(PVOP)的两种新型M(dmit)_2盐(M = Ni和Pd,(dmit = 1,3-二孔-2-硫酮-4,5-二硫醇盐)) )作为抗衡阳离子的合成。通过电化学沉积法制备了由这些盐衍生的半导体薄膜。 Ni(dmit)_2膜显示出非常光滑且均匀的表面。通过使用PVOP作为抗衡阳离子,Ni(dmit)_2盐的成膜性能得到了显着改善。

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