Polymerization of Pyrrole under Microgravity Conditions

Y.Abe; N.Takamatsu; T.Yumoto

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Polymerization of Pyrrole under Microgravity Conditions

机译：微重力条件下吡咯的聚合

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Oxidative polymerization of pyrrole derivatives in a microgravity environment was carried out using the JAMIC drop shaft where 10-s microgravity condition is available. Although the polymerization reaction did not finish during the microgravity condition, The polymers have some unique features compared to those obtained under normal Gravity conditions. The physical properties of the polymers were examined and possible Origins of the unique features were discussed.

机译：使用可在10 s微重力条件下使用的JAMIC滴井在微重力环境中进行吡咯衍生物的氧化聚合。尽管在微重力条件下聚合反应未完成，但与在正常重力条件下获得的聚合物相比，该聚合物具有一些独特的功能。检查了聚合物的物理性质，并讨论了独特特征的可能来源。

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《Space Forum》 |2000年第4期|p.221-226|共6页
作者
Y.Abe; N.Takamatsu; T.Yumoto;
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原文格式 PDF
正文语种 eng
中图分类航天（宇宙航行）;
关键词
Polypyrrole and derivatives; Infrared spectroscopy; UV-Vis-NIR spectroscopy;

机译：聚吡咯及其衍生物;红外光谱紫外-可见-近红外光谱;

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专利

1. Polymerization of pyrrole in microgravity [J] . Nakamura T., Hasegawa T., Kikukawa T., Synthetic Metals . 1999,第1a3期

机译：吡咯在微重力下的聚合
2. PROCESSING OF POLED SECOND-ORDER NONLINEAR OPTICAL POLYMER SYSTEMS UNDER MICROGRAVITY CONDITIONS [J] . L. H. DAO, K. PARBHAKAR, H. M. NGUYEN, Acta astronautica . 2002,第10期

机译：微重力条件下POLED二阶非线性光学聚合物体系的制备
3. Polymerization under microgravity conditions: results and perspectives [J] . V. A. Briskman, K. G. Kostarev Polymer Preprints . 2000,第1期

机译：微重力条件下的聚合：结果和观点
4. Soft Actuators Prepared by Electrochemical Copolymerization of Pyrrole and Methyl 1H-Pyrrole-3-carboxylate [C] . Jun Yamasaki, Shou Ogihara, Telsuya Kadoyama, Symposium on Sensors, Actuators, and Microsystems General Session;Meeting of The Electrochemical Society . 2014

机译：吡咯与1H-吡咯-3-羧酸甲酯的电化学共聚制备的软促动器
5. New developments toward the synthesis of heterocycles and applications in green chemistry. I. A simple and essentially one-pot synthesis of N-aminated heterocycles using phase transfer catalyst (Aliquat-336). II. Synthesis of pharmaceutically important pyrrole derivatives. III. Applications in green chemistry: Surfactant-mediated environmentally friendly cleavage of aromatic esters and trans-esterification under solvent-free neutral conditions . [D] . Patel, Nitinchandra. 2005

机译：杂环合成的新进展及其在绿色化学中的应用。 I.使用相转移催化剂（Aliquat-336）简单且基本上一锅合成N-胺化的杂环。二。药学上重要的吡咯衍生物的合成。三，在绿色化学中的应用：在无溶剂的中性条件下，表面活性剂介导的环境友好的芳族酯裂解和酯交换反应。
6. Preparation of a DNA matrix via an electrochemically directed copolymerization of pyrrole and oligonucleotides bearing a pyrrole group. [O] . T Livache, A Roget, E Dejean, 1994

机译：通过吡咯和带有吡咯基团的寡核苷酸的电化学定向共聚制备DNA基质。
7. Vinyl Polymers Bearing a Pyrrole Ring. II. 5,10,15,20-Tetraphenylporphyrins with a Substituent-Bearing Vinyl Group at the Pyrrole Residue and Their Zinc Complexes [O] . Hiroyoshi Kamogawa, Takuharu Nakata, Sei Komatsu 1991

机译：含有吡咯环的乙烯基聚合物。 II。用吡咯残基的含有取代基乙烯基及其锌络合物的5,10,15,20-四苯基卟啉
8. Polymerization of Conducting Polymers Confined to Free Surfaces: A Comparison of the Langmuir-Blodgett Polymerization of 3-Alkyl Pyrroles and 2-Alkyl Anilines. [R] . Zhou, H. C., Duran, R. S. 1992

机译：限制在自由表面的导电聚合物的聚合：3-烷基吡咯和2-烷基苯胺的Langmuir-Blodgett聚合的比较。

Polymerization of Pyrrole under Microgravity Conditions

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