Time resolved spectroelectrochemistry studies for protection of heritage metals

Adriaens A.; Dowsett M.

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Time resolved spectroelectrochemistry studies for protection of heritage metals

机译：时间分辨光谱电化学研究，用于保护传统金属

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This paper discusses the evaluation of metal conservation treatments using a specialised electrochemical cell. The cell can be deployed in a synchrotron beam line to make in situ, time resolved, measurements on heritage metal alloys undergoing processes based on immersion in aqueous treatment solutions, electrochemical treatments/measurements. The present paper focuses on two specific projects: the evaluation of corrosion potential data as a simple monitoring method during the stabilisation of cupreous objects recovered from marine environments and the development and testing of a coating to protect lead objects which is stable, reversible (i.e. easy to apply and to remove), protective against corrosion and aesthetically justified.

机译：本文讨论了使用专门的电化学电池对金属保存处理的评估。该电池可以部署在同步加速器射线束中，以便对正在进行的基于浸入水处理溶液，电化学处理/测量过程的传统金属合金进行原位，时间分辨和测量。本文着重于两个具体项目：腐蚀电位数据的评估，作为稳定从海洋环境中回收的铜质物体期间的一种简单监测方法，以及开发和测试一种保护铅质物体的涂层，该涂层稳定，可逆（即容易）。应用和移除），防腐蚀和美观。

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《Surface Engineering》 |2008年第2期|p.84-89|共6页
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Adriaens A.; Dowsett M.;
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1. Time resolved spectroelectrochemistry studies for protection of heritage metals [J] . A. Adriaens, M. Dowsett Surface Engineering . 2008,第2期

机译：时间分辨光谱电化学研究，用于保护传统金属
2. The Coordinated Use of Synchrotron Spectroelectrochemistry for Corrosion Studies on Heritage Metals [J] . Annemie Adriaens and Mark Dowsett Accounts of Chemical Research . 2010,第6期

机译：同步光谱电化学在传统金属腐蚀研究中的协同使用
3. Excited States of Nitro-Polypyridine Metal Complexes and Their Ultrafast Decay.Time-Resolved IR Absorption,Spectroelectrochemistry,and TD-DFT Calculations of fac-[Re(Cl)(CO)_3(5-Nitro-l,10-phenanthroline)] [J] . Anders Gabrielsson, Pavel Matousek, Michael Towrie, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第28期

机译：硝基吡啶金属配合物的激发态及其超快衰减。fac-[Re（Cl）（CO）_3（5-硝基-1,10-菲咯啉）]的时间分辨红外吸收，光谱电化学和TD-DFT计算
4. Time resolved XANES illustrates a substrate-mediated redox process in Prussian blue cultural heritage materials [C] . Claire Gervais, Marie-Angelique Lanquille, Giulia Moretti, International Conference on X-ray Absorption Fine Structure . 2015

机译：定期分辨的Xanes说明了普鲁士蓝色文化遗产材料中的衬底介导的氧化还原过程
5. A NEW METHOD TO STUDY TRANSPORT ACROSS MEMBRANES AND INTERFACES USING SPACIALLY RESOLVED SPECTROSCOPY WITH LASER EXCITATION AND DIODE ARRAY DETECTION (ELECTROCHEMISTRY, SPECTROELECTROCHEMISTRY) [D] . COUCH, RICHARD ALAN 1986

机译：激光激发和二极管阵列检测的空间分辨光谱法研究跨膜和跨界面传输的新方法（电子，光谱
6. Time-Resolved Photoluminescence Spectroscopy and Imaging: New Approaches to the Analysis of Cultural Heritage and Its Degradation [O] . Austin Nevin, Anna Cesaratto, Sara Bellei, 2014

机译：时间分辨的光致发光光谱学和成像：文化遗产及其退化分析的新方法
7. Time resolved spectroelectrochemistry studies for protection of heritage metals [O] . Adriaens Mieke, DOWSETT M 2008

机译：时间分辨光谱电化学研究保护遗产金属
8. Time-Resolved Infrared Spectroelectrochemistry [R] . Pons, S., Daschbach, J., Heisler, D. 1986

机译：时间分辨红外光谱电化学

Time resolved spectroelectrochemistry studies for protection of heritage metals

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