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首页> 外文期刊>Thin Solid Films >Hard coating films based on organosilane-modified boehmite nanoparticles under UV/thermal dual curing
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Hard coating films based on organosilane-modified boehmite nanoparticles under UV/thermal dual curing

机译:在紫外线/热双重固化下基于有机硅烷改性勃姆石纳米颗粒的硬质涂膜

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摘要

Hard coating sols and films were prepared for UV/thermal dual curing. The coating sols were composed of boehmite nanoparticles modified with organosilanes (e.g. methacryloxy-propyl trimethoxy silane, Ⅵnyl triethoxy silane, and 3-glycidoxy-propyltrimethoxy silane), a formulated initiator, and an inorganic or organic cross-linker as an additive. With this coating solution, hard coating films with a pencil hardness above 8H and transparency above 90% in the Ⅵsible light range were prepared on poly(methyl methacrylate) substrates. In addition, the coating solution could be quickly cured in 35 min at a temperature of 100 ℃ by UV/thermal dual curing. The effects of the additive and initiator on the hardness and transparency of the resulting films are described.
机译:制备硬涂层溶胶和薄膜以进行UV /热双重固化。涂料溶胶由用有机硅烷(例如甲基丙烯酰氧基-丙基三甲氧基硅烷,乙烯基三乙氧基硅烷和3-环氧丙氧基-丙基三甲氧基硅烷)改性的勃姆石纳米颗粒,配制的引发剂和无机或有机交联剂作为添加剂组成。用这种涂料溶液,在聚甲基丙烯酸甲酯基底上制备了铅笔硬度在8H以上,在可见光范围内透明度在90%以上的硬质涂膜。此外,该涂料溶液可以在35分钟内于100℃的温度下通过UV /热双重固化快速固化。描述了添加剂和引发剂对所得膜的硬度和透明度的影响。

著录项

  • 来源
    《Thin Solid Films》 |2008年第12期|3904-3909|共6页
  • 作者单位

    Hybrid Nanoparticle Laboratory, Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 133-791, Republic of Korea;

    Hybrid Nanoparticle Laboratory, Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 133-791, Republic of Korea;

    Hybrid Nanoparticle Laboratory, Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 133-791, Republic of Korea;

    Hybrid Nanoparticle Laboratory, Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 133-791, Republic of Korea;

    Hybrid Nanoparticle Laboratory, Department of Chemical Engineering, College of Engineering, Hanyang University, Seoul 133-791, Republic of Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    boehmite znanoparticle; organosilane; hard coating; UV/thermal curing; scanning electron microscopy; wear; infrared spectroscopy;

    机译:勃姆石纳米颗粒;有机硅烷硬涂层紫外线/热固化;扫描电子显微镜;穿;红外光谱;

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