Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

F. Banishoeib; A. Henckens; S. Fourier; G. Vanhooyland; M. Breselge; J. Manca; T.J. Cleij; L. Lutsen; D. Vanderzande; Le Huong Nguyen; Helmut Neugebauer; Niyazi Serdar Sariciftci

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Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

机译：聚（2,5-亚噻吩乙烯）及其衍生物的合成：用于光伏的低带隙材料

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Poly-(2,5-Thienylene Vinylene) (PTV) derivatives have been synthesised via the "dithiocarbamate precursor route" in good yield and satisfactory molecular weight. Structural characterisations of the conjugated PTV polymers reveal an optical band gap around 1.8 eV. Organic field effect transistors and organic based photovoltaic devices were made with the plain PTV, via a precursor approach. More specifically, solar cells were produced using a blend of the precursor PTV polymer and PCBM (1-(3-methoxycarbonyl) propyl-1-phenyl [6,6] C_(61)) at various ratios, converted in situ in thin film. A promising power efficiency of 0.76% was achieved.

机译：经由“二硫代氨基甲酸酯前体途径”已经以良好的产率和令人满意的分子量合成了聚（2，5-亚噻吩乙烯基）（PTV）衍生物。共轭PTV聚合物的结构表征显示出1.8 eV附近的光学带隙。通过普通的PTV，通过前驱方法制造了有机场效应晶体管和基于有机的光电器件。更具体地，使用前体PTV聚合物和PCBM（1-（3-甲氧基羰基）丙基-1-苯基[6,6] C_（61））的混合物以各种比例生产太阳能电池，并在薄膜中原位转化。。达到了有希望的0.76％的电源效率。

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来源
《Thin Solid Films》 |2008年第12期|3978-3988|共11页
作者
F. Banishoeib; A. Henckens; S. Fourier; G. Vanhooyland; M. Breselge; J. Manca; T.J. Cleij; L. Lutsen; D. Vanderzande; Le Huong Nguyen; Helmut Neugebauer; Niyazi Serdar Sariciftci;
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作者单位

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium IMEC, IMOMEC division, Wetenschapspark I, B-3590 Diepenbeek, Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium;

IMEC, IMOMEC division, Wetenschapspark I, B-3590 Diepenbeek, Belgium;

Hasselt University, Institute of Material Research (IMO), Agoralaan, Building D, B-3590 Diepenbeek Belgium IMEC, IMOMEC division, Wetenschapspark I, B-3590 Diepenbeek, Belgium;

Linz Institute for Organic Solar Cells (LIOS), Johannes Kepler University, Altenbergerstr. 69, A-4040 Linz, Austria;

Linz Institute for Organic Solar Cells (LIOS), Johannes Kepler University, Altenbergerstr. 69, A-4040 Linz, Austria;

Linz Institute for Organic Solar Cells (LIOS), Johannes Kepler University, Altenbergerstr. 69, A-4040 Linz, Austria;

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正文语种 eng
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low band gap; conjugated polymer; precursor polymer; poly-(2,5-thienylene vinylene);

机译：低带隙共轭聚合物前体聚合物;聚-（2,5-亚噻吩基亚乙烯基）;

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专利

1. The synthesis of poly(thienylene vinylene) derivatives via the dithiocarbamate route: low band gap p-type conjugated polymers for photovoltaics [J] . Banishoeib F, Fourier S, Cleij TJ, The European physical journal. Applied physics . 2007,第3期

机译：通过二硫代氨基甲酸酯途径合成聚（亚噻吩乙烯撑）衍生物：用于光伏的低带隙p型共轭聚合物
2. Poly(thienylene vinylene) derivatives as low band gap polymers for photovoltaic applications [J] . A. Henckens, M. Knipper, I. Polec, Thin Solid Films . 2004,第Mar期

机译：聚（亚乙撑亚乙烯基）衍生物作为光伏应用的低带隙聚合物
3. Low Band Gap Poly(thienylene vinylene)/Fullerene Bulk Heterojunction Photovoltaic Cells [J] . Jung Yong Kim, Yang Qin, Derek M. Stevens The journal of physical chemistry, C. Nanomaterials and interfaces . 2009,第24期

机译：低带隙聚（亚乙撑乙烯基）/富勒烯本体异质结光伏电池
4. Low bandgap Poly(Thienylene Vinylene) for Organic Solar Cells: Photophysics and Photovoltaic Performance [C] . Le Huong Nguyen, Scrap Guenes, Helmut Neugebauer, Organic Optoelectronics and Photonics II . 2006

机译：适用于有机太阳能电池的低带隙聚（亚乙撑乙烯基）：光物理性质和光伏性能
5. Poly(1,3 -dithienylisothianaphthene) derivatives: Synthesis, characterisation and possible applications of a new class of low -bandgap materials [D] . Vangeneugden, Dirk Leo 1999

机译：聚（1,3-二噻吩基异亚锡菲）衍生物：新型低带隙材料的合成，表征及可能的应用
6. Low-Temperature Synthesis of Bismuth Chalcohalides: Candidate Photovoltaic Materialswith Easily Continuously Controllable Band gap [O] . Hironobu Kunioku, Masanobu Higashi, Ryu Abe -1

机译：卤化铋的低温合成：候选光伏材料轻松可连续控制的带隙
7. Low-Temperature Synthesis of Bismuth Chalcohalides: Candidate Photovoltaic Materialswith Easily, Continuously Controllable Band gap [O] . Hironobu Kunioku, Masanobu Higashi, Ryu Abe 2016

机译：低温合成铋Chalcohalides：候选光伏料理可容易，可持续可控的带隙
8. Isomeric Poly(benzophenone)s: Synthesis of Highly Crystalline Poly(4,4'-benzophenone) and Amorphous Poly(2,5-benzophenone), a Soluble Poly(p-phenylene) Derivative [R] . Phillips, R. W., Sheares, V. V., Samulski, E. T., 1994

机译：异构聚（二苯甲酮）：高结晶聚（4,4'-二苯甲酮）和无定形聚（2,5-二苯甲酮），可溶性聚（对亚苯基）衍生物的合成

Synthesis of poly(2,5-Thienylene Vinylene) and its derivatives: Low band gap materials for photovoltaics

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