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首页> 外文期刊>Thin Solid Films >Polymer solar cells with low-bandgap polymers blended with C_(70)-derivative give photocurrent at 1 μm
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Polymer solar cells with low-bandgap polymers blended with C_(70)-derivative give photocurrent at 1 μm

机译:低带隙聚合物与C_(70)衍生物混合的聚合物太阳能电池的光电流为1μm

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摘要

A new series of low-bandgap alternating polyfluorenes with different donor-acceptor-donor moieties have been synthesized. Electrochemical and optical absorption measurement show that onset bandgaps of these polymers range from 1.2 to 1.5 eV. These polymers, blended with a C_(70)-derivative as acceptor, are used for solar cell fabrication. Devices show promising photovoltaic properties, and the spectral response of photocurrent covers all visible and near-infrared wavelength regions with its onset extended to 1 μm. The best data gives a photocurrent density of 3.4 mA/cm~2, open circuit voltage of 0.58 Vand power conversion efficiency of 0.7% under illumination of AM1.5 (1000 W/m~2) from a solar simulator.
机译:合成了具有不同供体-受体-供体部分的一系列新的低带隙交替聚芴。电化学和光吸收测量表明,这些聚合物的起始带隙为1.2至1.5 eV。这些聚合物与C_(70)衍生物作为受体共混,用于太阳能电池的制造。器件显示出令人鼓舞的光伏特性,并且光电流的光谱响应涵盖了所有可见光和近红外波长区域,并且其起始点扩展到了1μm。最好的数据是在太阳模拟器的AM1.5(1000 W / m〜2)光照下,光电流密度为3.4 mA / cm〜2,开路电压为0.58 V,功率转换效率为0.7%。

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