Synthesis and photoluminescence of poly(3-hexylthiophene)/titania nanostructured hybrids

Jr-Shian Ji; Yi-Jun Lin; Hsueh-Pei Lu; Leeyih Wang; Syang-Peng Rwei

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Synthesis and photoluminescence of poly(3-hexylthiophene)/titania nanostructured hybrids

机译：聚（3-己基噻吩）/二氧化钛纳米结构杂化物的合成与光致发光

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Novel poly(3-hexylthiophene)/titania hybrids were synthesized by the sol-gel process using titanium(Ⅳ) isopropoxide as a precursor in the presence of silane-bearing poly(3-hexylthiophene), which was prepared from the copolymerization of 3-hexylthiophene and 3-thienylmethyl-N-triethoxylsilylpropyl amide monomers. The chemical structure of these materials was characterized by FT-IR and ~1H NMR. SEM micrographs demonstrated that the TiO_2 nanoparticles were evenly distributed within the hybrid materials. The energy levels of the hybrid material were determined from cyclic voltammagrams (CV) and UV-vis spectra. Photoluminescence spectra imply that the photo-induced electron transfer is more efficient in silane-bearing poly(3-hexylthiophene)/TiO_2 than in poly(3-hexylthiophene)/TiO_2.

机译：在含有硅烷的聚（3-己基噻吩）存在下，通过异丙醇钛（Ⅳ）为前驱体，通过溶胶-凝胶法合成了新型聚（3-己基噻吩）/二氧化钛杂化物。己基噻吩和3-噻吩基甲基-N-三乙氧基甲硅烷基丙基酰胺单体。这些材料的化学结构通过FT-IR和〜1H NMR表征。 SEM显微照片表明，TiO_2纳米颗粒均匀分布在杂化材料中。杂化材料的能级由循环伏安图（CV）和紫外可见光谱确定。光致发光光谱表明，在含硅烷的聚（3-己基噻吩）/ TiO_2中，光诱导的电子转移比在聚（3-己基噻吩）/ TiO_2中更有效。

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来源
《Thin Solid Films》 |2006年第7期|p.182-186|共5页
作者
Jr-Shian Ji; Yi-Jun Lin; Hsueh-Pei Lu; Leeyih Wang; Syang-Peng Rwei;
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作者单位

Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei, Taiwan;

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原文格式 PDF
正文语种 eng
中图分类工程材料学;
关键词
polymer/titania hybrids; silane-containing polythiophene; conductive polymers; photoluminescence;

机译：聚合物/二氧化钛杂化物;含硅烷的聚噻吩;导电聚合物;光致发光;

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2. Understanding the mechanism of poly(3-hexylthiophene)-b-poly(4-vinylpyridine) as a nanostructuring compatibilizer for improving the performance of poly(3-hexylthiophene)/ZnO-based hybrid solar cells [J] . Kai Yuan, Fan Li, Lie Chen Journal of Materials Chemistry, A. Materials for energy and sustainability . 2013,第36期

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3. Atomistic Investigation of Poly(3-hexylthiophene) Adhesion on Nanostructured Titania [J] . Claudio Melis, Alessandro Mattoni, Luciano Colombo The journal of physical chemistry, C. Nanomaterials and interfaces . 2010,第8期

机译：聚（3-己基噻吩）在纳米结构二氧化钛上的粘附原子研究
4. Synthesis, mobility, and conductivity of well-defined regioregular poly(3-hexylthiophene) and diblock copolymers of regioregular poly(3-hexylthiophene) [C] . Genevieve Sauve, Rui Zhang, Shijun Jia, Organic Field-Effect Transistors V . 2006

机译：定义明确的区域规则的聚（3-己基噻吩）和区域规则的聚（3-己基噻吩）的二嵌段共聚物的合成，迁移率和电导率
5. Synthesis of Bridged Calix[4]arenes by Selective Functionalization at the Lower Rim and Synthesis of Block Copolymers Containing Poly(3-hexylthiophene). [D] . Hailu, Shimelis T. 2012

机译：通过在较低的边缘选择性官能化合成桥接的杯[4]芳烃和合成含聚（3-己基噻吩）的嵌段共聚物。
6. An ultraviolet responsive hybrid solar cell based on titania/poly(3-hexylthiophene) [O] . Jihuai Wu, Gentian Yue, Yaoming Xiao, -1

机译：基于二氧化钛/聚（3-己基噻吩）的紫外线响应型混合太阳能电池
7. Atomistic investigation of the poly(3-hexylthiophene) adhesion on nanostructured titania [O] . Claudio Melis, Ro Mattoni, Luciano Colombo 2016

机译：纳米结构二氧化钛上聚（3-己基噻吩）粘附的原子研究

Synthesis and photoluminescence of poly(3-hexylthiophene)/titania nanostructured hybrids

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