Polymer Design and Nano-structure Analysis of The Super Olefin Polymer

Takao Nomura; Masatoshi Matsuda; Takayuki Nagai

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Polymer Design and Nano-structure Analysis of The Super Olefin Polymer

机译：超级烯烃聚合物的聚合物设计和纳米结构分析

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The nano-structure of The Super Olefin Polymer (TSOP) was examined by transmission electron microscope, wide-angle X-ray diffraction, and small-angle X-ray scattering. It was recognized that polypropylene crystals grow precisely in the direction perpendicular to the surface of moldings in the form of rectangular pillars about 12 nanometers wide. The polymer design for the formation of this crystalline structure can be sumarized in terms of three factors. The first is the formation of an elastomer matrix structure by using propylene-rich ethylene-propylene rubber.

机译：通过透射电子显微镜，广角X射线衍射和小角X射线散射检查了超级烯烃聚合物（TSOP）的纳米结构。公认的是，聚丙烯晶体以垂直于模制品表面的方向以约12纳米宽的矩形柱形式精确地生长。用于形成该晶体结构的聚合物设计可以根据三个因素进行总结。首先是通过使用富含丙烯的乙烯-丙烯橡胶形成弹性体基质结构。

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来源
《Toyota Technical Review》 |1998年第1期|p.27-34|共8页
作者
Takao Nomura; Masatoshi Matsuda; Takayuki Nagai;
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原文格式 PDF
正文语种 eng
中图分类汽车工程;一般工业技术;
关键词
TSOP; polypropylene; nano-structure;

机译：TSOP;聚丙烯;纳米结构;

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专利

1. Superior Cascade Ring-Opening/Ring-Closing Metathesis Polymerization and Multiple Olefin Metathesis Polymerization: Enhancing the Driving Force for Successful Polymerization of Challenging Monomers [J] . Lee Ho-Keun, Lee Jaeho, Kockelmann Johannes, Journal of the American Chemical Society . 2018,第33期

机译：优异的级联开环/闭环易位聚合和多烯烃易位聚合：增强具有挑战性单体成功聚合的驱动力
2. Activation of late transition metal catalysts for olefin polymerizations and olefin/CO copolymerizations [J] . Anselment TMJ, Vagin SI, Rieger B Dalton transactions: An international journal of inorganic chemistry . 2008,第34期

机译：用于烯烃聚合和烯烃/ CO共聚的后期过渡金属催化剂的活化
3. Microstructural Polymer Design through CoordinativePolymerization of Semi-Crystalline Poly-i-Olefins [J] . Hinnerk Gordon Becker Macromolecular symposia . 2009,第Null期

机译：通过半结晶聚-i-烯烃的配位聚合设计微结构聚合物
4. Design and analysis of prototype mould for micro- and nano-structure replication on polymer substrates [C] . D. S. Trifonova, K. Gr. Kostadinov, M. A. Al-Wahab International Conference on Multi-Material Micro Manufacture . 2009

机译：聚合物基材微纳米结构复制原型模具的设计与分析
5. Polymerization of fluoro-olefins in liquid and supercritical carbon dioxide. [D] . Romack, Timothy J. 1997

机译：液态烯烃和超临界二氧化碳中的氟烯烃聚合。
6. Homo-polymerization of α-Olefins and Co-polymerization of Higher α-Olefins with Ethylene in the Presence of CpTiCl2(OC6H4X-p)/MAO Catalysts (X = CH3 Cl) [O] . W. Skupinski, K. Nicinski, D. Jamanek, 2005

机译：在CpTiCl2（OC6H4X-p）/ MAO催化剂（X = CH3Cl）存在下α-烯烃的均聚和高级α-烯烃与乙烯的共聚
7. Study of Super Olefin Polymer by Nano-Order Structure. IX. Toughness of Super Olefin Polymer. [O] . Takeo NOMURA, Takeyoshi NISHIO, Kouichi HATADA, 1997

机译：纳米阶结构研究超烯烃聚合物。 IX。超烯烃聚合物的韧性。
8. STIR: Redox-Switchable Olefin Polymerization Catalysis: Electronically Tunable Ligands for Controlled Polymer Synthesis. [R] . Long, B. K. 2013

机译：sTIR：氧化还原 - 可转换的烯烃聚合催化：用于可控聚合物合成的电子可调谐配体。

Polymer Design and Nano-structure Analysis of The Super Olefin Polymer

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