Reactivity of free radicals in chain propagation reaction in the oxidation of octene-1

Nikipanchuk M.V.; Chernyak B.I.; Kozak S.I.

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Reactivity of free radicals in chain propagation reaction in the oxidation of octene-1

机译：辛烯-1氧化过程中自由基在链增长反应中的反应性

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摘要

Peroxy radical reactivity in the reaction of chain continuation at oxidation of octene-1 by molecular oxygen is investigated. Rate constants and activation energies of the reactions chain continuation with the participation of C-H and C=C bonds are determined.

机译：研究了分子氧对辛烯-1氧化过程中链连续反应中的过氧自由基反应性。确定了在C-H和C = C键的参与下，反应链连续的速率常数和活化能。

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《Украинский химический журнал》 |1999年第8期|p.139-144|共6页
作者
Nikipanchuk M.V.; Chernyak B.I.; Kozak S.I.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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2. Determining chemospecificity in reactions with chain transfer agent and corresponding radical via evaluation of molecular weight dependency of apparent comonomer reactivity ratios: free-radical copolymerization of vinyl acetate and dibutyl maleate (vol 6, pg 109759, 2016) [J] . Rahdar Seyed Saeid, Abdollahi Mahdi, Ahmadi Ebrahim, RSC Advances . 2016,第114期

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3. Determining chemospecificity in reactions with chain transfer agent and corresponding radical via evaluation of molecular weight dependency of apparent comonomer reactivity ratios: free-radical copolymerization of vinyl acetate and dibutyl maleate (vol 6, pg 109759, 2016) [J] . Rahdar Seyed Saeid, Abdollahi Mahdi, Ahmadi Ebrahim, RSC Advances . 2016,第114期

机译：通过评估表观共聚单体反应比的分子量依赖性确定与链转移剂和相应自由基的反应中的化学专一性：乙酸乙烯酯和马来酸二丁酯的自由基共聚合（第6卷，第109759页，2016年）
4. Thermochemical Kinetic Analysis on Chain Branching in Alkyl Radical Reactions with O2: n-Propyl andHydroperoxide-Propyl Radicals [C] . Chiung-Chu Chen, Joseph W. Bozzelli Fourth Joint Meeting of the U.S. Sections of the Combustion Institute: Western States, Central States, Eastern States: Abstracts . 2005

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8. Vanadate-Stimulated Oxidation of NAD(P)H by Biomembranes is a Superoxide-Initiated Free Radical Chain Reaction [R] . Liochev, S., Fridovich, I. 1986

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Reactivity of free radicals in chain propagation reaction in the oxidation of octene-1

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