Pitzer approximation of the dependence of equilibrium constants of reactions on the complexing silica surface on the ionic strength of solutions

Kholin Y.V.; Bugaevskii A.A.; Konyaev D.S.

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Pitzer approximation of the dependence of equilibrium constants of reactions on the complexing silica surface on the ionic strength of solutions

机译：络合二氧化硅表面反应平衡常数对溶液离子强度的依赖性的Pitzer近似

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The Pitzer's method developed to estimate the mean activity coefficients for water electrolyte solutions was the base for creating a model describing equilibria on complexing silica surfaces. The model allows to approximate dependencies of concentrational and mixed equilibrium constants on a solution ionic strength and to evaluate thermodynamical equilibrium constants.

机译：用来估计水电解质溶液平均活度系数的Pitzer方法是创建描述复杂二氧化硅表面平衡的模型的基础。该模型可以近似估计溶液中离子浓度和混合平衡常数的依赖性，并可以评估热力学平衡常数。

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《Украинский химический журнал》 |1999年第8期|p.110-112|共3页
作者
Kholin Y.V.; Bugaevskii A.A.; Konyaev D.S.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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1. FORMATION CONSTANTS AT HIGH IONIC STRENGTH--II. THE IONIC STRENGTH CORRECTION OF FORMATION CONSTANTS USING A SIMPLIFIED PITZER EQUATION [J] . GRAHAM E. JACKSON, LISA F. SEYMOUR Talanta: The International Journal of Pure and Applied Analytical Chemistry . 1995,第1期

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2. Modeling of Protonation Constants of Linear Aliphatic Dicarboxylates Containing -S-Groups in Aqueous Chloride Salt Solutions, at Different Ionic Strengths, Using the SIT and Pitzer Equations and Empirical Relationships [J] . Clemente Bretti, Concetta De Stefano, Frank J. Millero, Journal of Solution Chemistry . 2008,第6期

机译：使用SIT和Pitzer方程及经验关系对不同离子强度下的含氯盐水溶液中含-S-基的直链脂肪族二羧酸酯的质子化常数进行建模
3. Modeling of protonation constants of linear aliphatic dicarboxylates containing -S-groups in aqueous chloride salt solutions, at different ionic strengths, using the SIT and pitzer equations and empirical relationships [J] . Bretti C., De Stefano C., Millero F.J., Journal of Solution Chemistry . 2008,第6期

机译：使用SIT和pitzer方程及经验关系，在不同离子强度下，在氯化物盐水溶液中含-S-的线性脂肪族二羧酸酯的质子化常数建模
4. The Effect of Addition of Primary Positive Salts, Complex Salt, on the Ionic Strength and Rate Constant at Various Temperatures by Reaction Kinetics [C] . S. S. Kurade, A. A. Ramteke International Conference on Condensed Matter and Applied Physics . 2017

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5. Metal adsorption onto oxides from aqueous solutions: The influence of the electrolyte, ionic strength and surface coverage on surface complexation. [D] . Criscenti, Louise Jacqueline. 2000

机译：金属从水溶液中吸附到氧化物上：电解质，离子强度和表面覆盖对表面络合的影响。
6. Estimation of medium effects on equilibrium constants in moderate and high ionic strength solutions at elevated temperatures by using specific interaction theory (SIT): Interaction coefficients involving Cl OH- and Ac- up to 200°C and 400 bars [O] . Yongliang Xiong 2006

机译：通过使用特定的相互作用理论（SIT）估算中等温度和高离子强度溶液在升高的温度下介质对平衡常数的中等影响：高达200°C和400 bar的涉及ClOH-和Ac-的相互作用系数
7. Effect of a molecular dipole on the ionic strength dependence of a biomolecular rate constant. Identification of the site of reaction. [O] . Koppenol, W H 1980

机译：分子偶极子对生物分子速率常数的离子强度依赖性的影响。识别反应部位。

Pitzer approximation of the dependence of equilibrium constants of reactions on the complexing silica surface on the ionic strength of solutions

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